| Yazarlar |
Tuncer Hökelek
Hacettepe Üniversitesi, Turkey |
|
Filiz Ylmaz
Anadolu Üniversitesi, Turkey |
|
Bar Tercan
Karabük Üniversitesi, Turkey |
Doç. Dr. Füreya Elif ÖZTÜRKKAN
Kafkas Üniversitesi, Türkiye |
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye |
| Özet |
| The asymmetric unit of the title compound, [Zn2(C7H 4FO2)4(C6H6N2O)2] ·C7H5FO2, consists of a binuclear ZnII complex bridged by two carboxyl groups of 2-fluoro-benzoate (FB) anions and a 2-fluoro-benzoic acid mol-ecule. The two bridging FB anions, one chelating FB anion and one nicotinamide (NA) ligand coordinate to one Zn cation with a distorted square-pyramidal geometry, while the two bridging FB anions, one monodentate FB anion and one NA ligand coordinate to the other Zn cation with a distorted tetra-hedral geometry. Within the binuclear mol-ecule, the pyridine rings are oriented at a dihedral angle of 19.41 (14)°. In the crystal structure, the uncoordinated 2-fluorobenzoic acid mol-ecules are linked by O - H⋯O hydrogen bonding, forming centrosymmetric supra-molecular dimers. Inter-molecular N - H⋯O hydrogen bonds link the complex mol-ecules into a three-dimensional network. The π-π contacts between nearly parallel pyridine and benzene rings [dihedral angles of 19.41 (14) and 12.72 (16)°, respectively, centroid-centroid distances = 3.701 (2) and 3.857 (3) Å] may further stabilize the crystal structure. The fluorine atoms in two FB ligands are disordered over two positions, with occupancy ratios of 0.70:0.30. |
| Anahtar Kelimeler |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | ESCI dergilerinde yayımlanan tam makale |
| Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS |
| Dergi ISSN | 2056-9890 |
| Makale Dili | İngilizce |
| Basım Tarihi | 12-2009 |
| Cilt No | 65 |
| Sayı | 12 |
| Doi Numarası | 10.1107/S1600536809048089 |
