Tetrakis[μ-4-(dimethylamino)benzoato-κ2O:O′]bis[(N,N-diethylnicotinamide-κN1)zinc(II)]
Yazarlar (5)
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
Hacettepe Üniversitesi, Türkiye
Hakan Dal Anadolu Üniversitesi, Türkiye
Bar Tercan
Karabük Üniversitesi, Türkiye
Karabük Üniversitesi, Türkiye
Özgür Aybirdi
Kafkas Üniversitesi, Türkiye
Kafkas Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(ESCI dergilerinde yayınlanan tam makale)
|
||
| Dergi Adı | Acta Crystallographica Section E Structure Reports Online | ||
| Dergi ISSN | 1600-5368 | ||
| Makale Dili | İngilizce | Basım Tarihi | 12-2009 |
| Cilt / Sayı / Sayfa | 65 / 12 / – | DOI | 10.1107/S1600536809047473 |
| Makale Linki | https://journals.iucr.org/e/issues/2009/12/00/xu2669/xu2669.pdf | ||
| Özet |
| The title mol-ecule, [Zn2(C9H10NO2) 4(C10H14N2O)2], is a centrosymmetric binuclear complex, with Zn atoms [Zn⋯Zn′ = 2.8927 (4) Å] bridged by four carboxyl-ate groups from the dimethyl-amino-benzoate (DMAB) ligands. The four carboxyl O atoms around the Zn atom form a distorted square-planar arrangement; the distorted square-pyramidal coordination geometry is completed by the pyridine N atom of the N,N-diethyl-nicotinamide (DENA) ligand. The Zn atom is displaced by 0.3326 (2) Å from the plane of the four O atoms, with an average Zn - O distance of 2.0416 (12) Å. The dihedral angles between the carboxyl-ate groups and the adjacent benzene rings are 5.31 (8) and 11.00 (9)°, while the pyridine ring is oriented at dihedral angles of 66.26 (6) and 37.88 (7)° with respect to the benzene rings. Weak intra-molecular C - H⋯O and inter-molecular C - H⋯π inter-actions are present. |
| Anahtar Kelimeler |
Science Direct
Tetrakis[μ-4-(dimethylamino)benzoato-κ2O:O′]bis[(N,N-diethylnicotinamide-κN1)zinc(II)]
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| WoS | 5 |
| SCOPUS | 6 |