Yazarlar |
Tuncer Hökelek
Hacettepe Üniversitesi, Turkey |
Filiz Ylmaz
Anadolu Üniversitesi, Turkey |
Bar Tercan
Karabük Üniversitesi, Turkey |
Doç. Dr. Mustafa SERTÇELİK
Kafkas Üniversitesi, Türkiye |
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye |
Özet |
In the title compound, [Zn(C8H5O3) 2(C6H6N2O)] n , the ZnII ion is tetrahedrally coordinated by two formyl-benzoate (FB) and one isonicotinamide (INA) ligands while symmetry-related FB ligands bridge adjacent ZnII ions, forming polymeric chains along the b axis. The carboxyl-ate groups in the two FB ions are twisted away from the attached benzene ring by 9.07 (2) and 26.2 (2)°. The two benzene rings of the FB ions are oriented at a dihedral angle of 81.30 (5)°. In the crystal, adjacent polymeric chains inter-act via N- H⋯O and C- H⋯O hydrogen bonds, π-π contacts between the formyl-benzoate rings [centroid-centroid distance = 3.7736 (8) Å] and weak C- H⋯π inter-actions, forming a three-dimensional network. |
Anahtar Kelimeler |
Makale Türü | Özgün Makale |
Makale Alt Türü | ESCI dergilerinde yayımlanan tam makale |
Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS |
Dergi ISSN | 2056-9890 |
Makale Dili | İngilizce |
Basım Tarihi | 11-2009 |
Cilt No | 65 |
Sayı | 11 |
Doi Numarası | 10.1107/S160053680904241X |