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catena-Poly[[(4-formylbenzoato-κO1)(isonicotinamide-κN1)zinc(II)]-μ-4-formylbenzoato-κ2O1:O1′]       
Yazarlar
Tuncer Hökelek
Hacettepe Üniversitesi, Turkey
Filiz Ylmaz
Anadolu Üniversitesi, Turkey
Bar Tercan
Karabük Üniversitesi, Turkey
Doç. Dr. Mustafa SERTÇELİK Doç. Dr. Mustafa SERTÇELİK
Kafkas Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye
Özet
In the title compound, [Zn(C8H5O3) 2(C6H6N2O)] n , the ZnII ion is tetrahedrally coordinated by two formyl-benzoate (FB) and one isonicotinamide (INA) ligands while symmetry-related FB ligands bridge adjacent ZnII ions, forming polymeric chains along the b axis. The carboxyl-ate groups in the two FB ions are twisted away from the attached benzene ring by 9.07 (2) and 26.2 (2)°. The two benzene rings of the FB ions are oriented at a dihedral angle of 81.30 (5)°. In the crystal, adjacent polymeric chains inter-act via N- H⋯O and C- H⋯O hydrogen bonds, π-π contacts between the formyl-benzoate rings [centroid-centroid distance = 3.7736 (8) Å] and weak C- H⋯π inter-actions, forming a three-dimensional network.
Anahtar Kelimeler
Makale Türü Özgün Makale
Makale Alt Türü ESCI dergilerinde yayımlanan tam makale
Dergi Adı ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
Dergi ISSN 2056-9890
Makale Dili İngilizce
Basım Tarihi 11-2009
Cilt No 65
Sayı 11
Doi Numarası 10.1107/S160053680904241X