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catena-Poly[[(4-formylbenzoato-κO1)(isonicotinamide-κN1)zinc(II)]-μ-4-formylbenzoato-κ2O1:O1′]      
Yazarlar
Tuncer Hokelek
Filiz Yilmaz
Baris Tercan
Mustafa Sertcelik
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi
Özet
In the title compound, [Zn(C8H5O3) 2(C6H6N2O)] n , the ZnII ion is tetrahedrally coordinated by two formyl-benzoate (FB) and one isonicotinamide (INA) ligands while symmetry-related FB ligands bridge adjacent ZnII ions, forming polymeric chains along the b axis. The carboxyl-ate groups in the two FB ions are twisted away from the attached benzene ring by 9.07 (2) and 26.2 (2)°. The two benzene rings of the FB ions are oriented at a dihedral angle of 81.30 (5)°. In the crystal, adjacent polymeric chains inter-act via N- H⋯O and C- H⋯O hydrogen bonds, π-π contacts between the formyl-benzoate rings [centroid-centroid distance = 3.7736 (8) Å] and weak C- H⋯π inter-actions, forming a three-dimensional network.
Anahtar Kelimeler
Makale Türü Özgün Makale
Makale Alt Türü ESCI dergilerinde yayımlanan tam makale
Dergi Adı ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
Dergi ISSN 2056-9890
Makale Dili İngilizce
Basım Tarihi 11-2009
Cilt No 65
Doi Numarası 10.1107/S160053680904241X
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
WoS 10
SCOPUS 10
Google Scholar 14
ResearchGate 1
catena-Poly[[(4-formylbenzoato-κO1)(isonicotinamide-κN1)zinc(II)]-μ-4-formylbenzoato-κ2O1:O1′]

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