Diaquabis(2-bromobenzoato-κO)bis(nicotinamide-κN1)nickel(II)
Yazarlar (5)
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
Filiz Ylmaz
Anadolu Üniversitesi, Türkiye
Baris Tercan
Karabük Üniversitesi, Türkiye
Doç. Dr. Füreya Elif ÖZTÜRKKAN
Kafkas Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(ESCI dergilerinde yayınlanan tam makale)
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| Dergi Adı | Acta Crystallographica Section E Structure Reports Online | ||
| Dergi ISSN | 1600-5368 | ||
| Makale Dili | İngilizce | Basım Tarihi | 07-2009 |
| Cilt / Sayı / Sayfa | 65 / 7 / – | DOI | 10.1107/S1600536809021710 |
| Makale Linki | https://doi.org/10.1107/s1600536809021710 | ||
| Özet |
| The title NiII complex, [Ni(C7H4BrO 2)2(C6H6N2O) 2(H2O)2], is centrosymmetric. It contains two 2-bromo-benzoate (BB) ligands, two nicotinamide (NA) ligands and two water molecules, all of them being monodentate. The four O atoms in the equatorial plane around the Ni atom form a slightly distorted square-planar arrangement, while the slightly distorted octa-hedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxyl-ate group and the adjacent benzene ring is 30.81 (17)°, while the pyridine and benzene rings are oriented at a dihedral angle of 84.66 (6)°. In the crystal structure, O - H⋯O and N - H⋯O hydrogen bonds link the molecules into a supra-molecular structure. A weak C - H⋯π inter-action is also found. |
| Anahtar Kelimeler |
Science Direct
Diaquabis(2-bromobenzoato-κO)bis(nicotinamide-κN1)nickel(II)
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| WoS | 10 |
| SCOPUS | 10 |
| ResearchGate | 36 |