Diaquabis[4-(dimethylamino)benzoato]-κ2O,O′;κO-(isonicotinamide-κN1)cobalt(II)

Hökelek, Tuncer; Dal, Hakan; Tercan, Bar; Aybirdi, Zgür; NECEFOĞLU, HACALİ

doi:10.1107/S1600536809016602

Diaquabis[4-(dimethylamino)benzoato]-κ²O,O′;κO-(isonicotinamide-κN¹)cobalt(II)

Yazarlar (5)

Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye

Prof. Dr. Hakan Dal Anadolu Üniversitesi, Türkiye

Bar Tercan
Karabük Üniversitesi, Türkiye

Zgür Aybirdi
Kafkas Üniversitesi, Türkiye

Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye

Makale Türü	Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı	Acta Crystallographica Section E Structure Reports Online (Q4)
Dergi ISSN	1600-5368 Dergi Bilgileri (2009)
Makale Dili	İngilizce	Basım Tarihi	06-2009
Cilt / Sayı / Sayfa	65 / 6 / –	DOI	10.1107/S1600536809016602
Makale Linki	https://doi.org/10.1107/s1600536809016602
UAK Araştırma Alanları	Fen Bilimleri ve Matematik

Özet

The title Co^II complex, [Co(C9H10NO 2)2(C6H6N2O)(H 2O)2], contains two 4-dimethyl-amino-benzoate (DMAB) anions, one isonicotinamide (INA) ligand and two coordinated water mol-ecules. One of the DMAB anions acts as a bidentate ligand, while the other is monodentate. The four O atoms in the equatorial plane around the Co atom form a highly distorted square-planar arrangement, while the distorted octa-hedral coordination geometry is completed by the N atom of the INA ligand and the O atom of the second water mol-ecule in the axial positions. An intra-molecular O - H⋯O hydrogen bond between the monodentate-coordinated carboxyl group and a coordinated water mol-ecule results in a six-membered ring with an envelope conformation. The dihedral angles between the carboxyl groups and the adjacent benzene rings are 4.29 (10)° for the monodentate ligand and 2.31 (13)° for the bidentate ligand, while the two benzene rings are oriented at a dihedral angle of 65.02 (5)°. The dihedral angles between the pyridine and benzene rings are 11.21 (5)° for the monodentate ligand and 74.60 (5)° for the bidentate ligand. In the crystal structure, inter-molecular O - H⋯O, O - H⋯N and N - H⋯O hydrogen bonds link the mol-ecules into a supra-molecular structure.

Anahtar Kelimeler

Science Direct

BM Sürdürülebilir Kalkınma Amaçları

Atıf Sayıları
Web of Science	22
Scopus	23

Diaquabis[4-(dimethylamino)benzoato]-κ²O,O′;κO-(isonicotinamide-κN¹)cobalt(II)

Dergi Adı	ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
Kısa Adı	ACTA CRYSTALLOGR E
Yayıncı	WILEY-BLACKWELL PUBLISHING, INC
Açık Erişim	Evet
ISSN	1600-5368
E-ISSN	2056-9890
Wos Quartile	Q4
Scopus Quartile	Q3
Tarandığı Indeksler	SCIE , Scopus
WoS Kategoriler	CRYSTALLOGRAPHY
Scopus Kategoriler	CHEMISTRY (MISCELLANEOUS) \| MATERIALS SCIENCE (MISCELLANEOUS) \| CONDENSED MATTER PHYSICS

Diaquabis[4-(dimethylamino)benzoato]-κ2O,O′;κO-(isonicotinamide-κN1)cobalt(II)

Paylaş

Diaquabis[4-(dimethylamino)benzoato]-κ²O,O′;κO-(isonicotinamide-κN¹)cobalt(II)