| Yazarlar |
Tuncer Hokelek
|
|
Hakan Dal
|
|
Baris Tercan
|
|
Oezguer Aybirdi
|
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi |
| Özet |
| The title NiII complex, [Ni(C8H8NO2)2(C6H6N2O)2(H2O)2], is centrosymmetric with the Ni atom on an inversion center. The mol-ecule contains two 4-methyl-amino-benzoate (MAB) and two nicotinamide (NA) ligands and two coordinated water mol-ecules, all ligands being monodentate. The four O atoms in the equatorial plane around the Ni atom form a slightly distorted square-planar arrangement, while the slightly distorted octa-hedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxyl-ate group and the adjacent benzene ring is 2.09 (14)°, while the pyridine and benzene rings are oriented at a dihedral angle of 66.15 (4)°. In the crystal structure, inter-molecular O - H⋯O and N - H⋯O hydrogen bonds link the mol-ecules into a three-dimensional network. |
| Anahtar Kelimeler |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | ESCI dergilerinde yayımlanan tam makale |
| Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS |
| Dergi ISSN | 2056-9890 |
| Makale Dili | İngilizce |
| Basım Tarihi | 05-2009 |
| Cilt No | 65 |
| Sayı | 5 |
| Doi Numarası | 10.1107/S1600536809015633 |
| Atıf Sayıları | |
| WoS | 2 |
| SCOPUS | 2 |
