| Yazarlar |
Tuncer Hokelek
|
|
Hakan Dal
|
|
Baris Tercan
|
|
F. Elif Ozbek
|
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi |
| Özet |
| In the mononuclear title compound, [Co(C7H4BrO 2)2(C10H14N2O) 2(H2O)2], the CoII ion is located on a crystallographic inversion center. The asymmetric unit is completed by one 2-bromobenzoate anion, one diethylnicotinamide (DENA) ligand and one coordinated water molecule; all ligands are monodentate. The four O atoms in the equatorial plane around CoII form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two pyridine N atoms of the DENA ligands in axial positions. The dihedral angle between the carboxylate group and the attached benzene ring is 84.7 (1)°; the pyridine and benzene rings are oriented at a dihedral angle of 43.64 (6)°. In the crystal structure, intermolecular O-H⋯O and C-H⋯O hydrogen bonds link the molecules into a three-dimensional network. |
| Anahtar Kelimeler |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | ESCI dergilerinde yayımlanan tam makale |
| Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE |
| Dergi ISSN | 2056-9890 |
| Makale Dili | İngilizce |
| Basım Tarihi | 50-2009 |
| Cilt No | 65 |
| Doi Numarası | 10.1107/S160053680901191X |
| Atıf Sayıları | |
| WoS | 9 |
| SCOPUS | 10 |
