Yazarlar |
Onur Şahin
Ondokuz Mayis Üniversitesi, Turkey |
Orhan Büyükgüngör
Ondokuz Mayis Üniversitesi, Turkey |
Dursun Ali Köse
Hacettepe Üniversitesi, Turkey |
Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye |
Özet |
The title compound, [Co(C7H5O3) 2(C6H6N2O)2(H 2O)2], forms a three-dimensional hydrogen-bonded supra-molecular structure. The CoII ion is in an octa-hedral coordination environment comprising two pyridyl N atoms, two carboxyl-ate O atoms and two O atoms from water mol-ecules. Inter-molecular N - H⋯O and O - H⋯O hydrogen bonds produce R 22(8), R 22(12) and R 22(14) rings, which lead to two-dimensional chains. An extensive three-dimensional supra-molecular network of C - H⋯O, N - H⋯O and O - H⋯O hydrogen bonds and C - H⋯π inter-actions is responsible for crystal structure stabilization. This study is an example of the construction of a supra-molecular assembly based on hydrogen bonds in mixed-ligand metal complexes. © 2008 International Union of Crystallography. |
Anahtar Kelimeler |
Makale Türü | Özgün Makale |
Makale Alt Türü | ESCI dergilerinde yayımlanan tam makale |
Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY |
Dergi ISSN | 2053-2296 |
Makale Dili | İngilizce |
Basım Tarihi | 10-2008 |
Cilt No | 64 |
Sayı | 10 |
Doi Numarası | 10.1107/S0108270108029521 |
Atıf Sayıları | |
WoS | 3 |
SCOPUS | 3 |
ResearchGate | 3 |