| Yazarlar |
Tuncer Hökelek
Hacettepe Üniversitesi, Turkey |
|
Nagihan Caylak
Sakarya Üniversitesi, Turkey |
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye |
| Özet |
| The monomeric title ZnII complex, [Zn(C7H4BrO2)2(H2O)2], contains two 4-bromo-benzoate (BB) ligands and two coordinated water mol-ecules around a ZnII atom on a twofold rotation axis. The BB ions act as bidentate ligands, with two very dissimilar coordination distances. The sixfold coordination around the ZnII may be described as highly distorted octa-hedral, with the two aqua ligands arranged cis. Hydrogen bonding involving the carboxyl-ate O atoms has an effect on the delocalization in the carboxyl-ate groups. In the crystal structure, inter-molecular O - H⋯O hydrogen bonds link the mol-ecules into chains parallel to the c axis and stacked along the b axis. |
| Anahtar Kelimeler |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | ESCI dergilerinde yayımlanan tam makale |
| Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS |
| Dergi ISSN | 2056-9890 |
| Makale Dili | İngilizce |
| Basım Tarihi | 03-2008 |
| Cilt No | 64 |
| Sayı | 3 |
| Doi Numarası | 10.1107/S1600536808003759 |
| Atıf Sayıları | |
| WoS | 4 |
| SCOPUS | 4 |
