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Diaquabis(4-bromobenzoato-κ2O,O′)-zinc(II)      
Yazarlar (3)
Tuncer Hökelek
Hacettepe Üniversitesi, Turkey
Nagihan Caylak
Sakarya Üniversitesi, Turkey
Prof. Dr. Hacali NECEFOĞLU Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye
Devamını Göster
Özet
The monomeric title ZnII complex, [Zn(C7H4BrO2)2(H2O)2], contains two 4-bromo-benzoate (BB) ligands and two coordinated water mol-ecules around a ZnII atom on a twofold rotation axis. The BB ions act as bidentate ligands, with two very dissimilar coordination distances. The sixfold coordination around the ZnII may be described as highly distorted octa-hedral, with the two aqua ligands arranged cis. Hydrogen bonding involving the carboxyl-ate O atoms has an effect on the delocalization in the carboxyl-ate groups. In the crystal structure, inter-molecular O - H⋯O hydrogen bonds link the mol-ecules into chains parallel to the c axis and stacked along the b axis.
Anahtar Kelimeler
Makale Türü Özgün Makale
Makale Alt Türü ESCI dergilerinde yayımlanan tam makale
Dergi Adı ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
Dergi ISSN 2056-9890
Makale Dili İngilizce
Basım Tarihi 03-2008
Cilt No 64
Sayı 3
Doi Numarası 10.1107/S1600536808003759
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
WoS 5
SCOPUS 5
Diaquabis(4-bromobenzoato-κ2O,O′)-zinc(II)

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