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Diaquabis(4-bromobenzoato-κ2O,O′)-zinc(II)     
Yazarlar
Tuncer Hokelek
Nagihan Caylak
Hacali Necefoglu
Özet
The monomeric title ZnII complex, [Zn(C7H4BrO2)2(H2O)2], contains two 4-bromo-benzoate (BB) ligands and two coordinated water mol-ecules around a ZnII atom on a twofold rotation axis. The BB ions act as bidentate ligands, with two very dissimilar coordination distances. The sixfold coordination around the ZnII may be described as highly distorted octa-hedral, with the two aqua ligands arranged cis. Hydrogen bonding involving the carboxyl-ate O atoms has an effect on the delocalization in the carboxyl-ate groups. In the crystal structure, inter-molecular O - H⋯O hydrogen bonds link the mol-ecules into chains parallel to the c axis and stacked along the b axis.
Anahtar Kelimeler
Makale Türü Özgün Makale
Makale Alt Türü ESCI dergilerinde yayımlanan tam makale
Dergi Adı ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
Dergi ISSN 2056-9890
Makale Dili İngilizce
Basım Tarihi 30-2008
Cilt No 64
Doi Numarası 10.1107/S1600536808003759
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
WoS 4
SCOPUS 4
Diaquabis(4-bromobenzoato-κ2O,O′)-zinc(II)

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