Crystal structure of bis(μ-3-nitrobenzoato)-κ3O,O′:O;κ3O:O,O′-bis[bis(3-cyanopyridine-κN1)(3-nitrobenzoato-κ2O,O′)cadmium]
Yazarlar (5)
Türkiye
Selçuk Üniversitesi, Türkiye
Doç. Dr. Güventürk UĞURLU
Kafkas Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
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| Makale Alt Türü | ESCI dergilerinde yayınlanan tam makale |
| Dergi Adı | Acta Crystallographica Section E Crystallographic Communications |
| Dergi ISSN | 2056-9890 Wos Dergi Scopus Dergi |
| Dergi Tarandığı Indeksler | Emerging Sources Citation Index |
| Makale Dili | Türkçe |
| Basım Tarihi | 02-2017 |
| Cilt No | 73 |
| Sayfalar | 413 / 416 |
| DOI Numarası | 10.1107/S2056989017002675 |
| Makale Linki | http://dx.doi.org/10.1107/s2056989017002675 |
| Özet |
| The asymmetric unit of the title compound,[Cd2 (C7H4NO4) 4 (C6H4N2) 4], contains one CdII atom, two 3-nitrobenzoate (NB) anions and two 3-cyanopyridine (CPy) ligands. The two CPy ligands act as monodentate N (pyridine)-bonding ligands, while the two NB anions act as bidentate ligands through the carboxylate O atoms. The centrosymmetric dinuclear complex is generated by application of inversion symmetry, whereby the CdII atoms are bridged by the carboxylate O atoms of two symmetry-related NB anions, thus completing the distorted N2O5 pentagonal–bipyramidal coordination sphere of each CdII atom. The benzene and pyridine rings are oriented at dihedral angles of 10.02 (7) and 5.76 (9), respectively. In the crystal, C—HÁÁÁN hydrogen bonds link the molecules, enclosing R2 2 (26) ring motifs, in which they are further linked via C—HÁÁÁO hydrogen bonds, resulting in a three-dimensional network. In addition,–stacking interactions between parallel benzene rings and between parallel pyridine rings of adjacent molecules [shortest centroid-to-centroid distances= 3.885 (1) and 3.712 (1) A, respectively], as well as a weak C—HÁÁÁ interaction, may further stabilize the crystal structure. |
| Anahtar Kelimeler |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Google Scholar | 3 |