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Synthesis and crystal structure of diaquabis(4-iodinebenzoato-kO)bis-(nicotinamide-kN)cobalt(II)  
Yazarlar
Onur Íahin
Ondokuz Mayis Üniversitesi, Turkey
Orhan Büyükgüngör
Ondokuz Mayis Üniversitesi, Turkey
Dursun Ali Köse
Hacettepe Üniversitesi, Turkey
 Füreya Elif ÖZTÜRKKAN Füreya Elif ÖZTÜRKKAN
Kafkas Üniversitesi, Türkiye
 Hacali NECEFOĞLU Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye
Özet
The title compound [Co(C7H4O2I)2(C10H14N2O)2(H2O)2] is a two-dimensional hydrogen-bonded supramolecular complex. The complex crystallizes in the triclinic space group P1 with unit-cell parameters a = 7.2964(13), b = 8.6047(17), c = 16.745(3)Å, α= 93.034(15), β = 101.574(15), γ = 111.975(14)° and Z = 1. The Co(II) ion resides on a centre of symmetry, and is in an octahedral coordination environment comprising two pyridyl N atoms, two carboxylate O atoms and two O atoms from water molecules. Intermolecular C-H·O and O-H···O hydrogen bonds produce R22(16), R22(18) and R22(20) rings, which lead to one-dimensional polymeric chains. An extensive two-dimensional network of C-H···O and O-H···O hydrogen bonds, p-p and C-H···π interactions are responsible for crystal stabilization. 2008 © The Japan Society for Analytical Chemistry.
Anahtar Kelimeler
Makale Türü Diğer (Teknik, not, yorum, vaka takdimi, editöre mektup, özet, kitap krıtiği, araştırma notu, bilirkişi raporu ve benzeri)
Makale Alt Türü SCOPUS dergilerinde yayımlanan teknik not, editöre mektup, tartışma, vaka takdimi ve özet türünden makale
Dergi Adı Analytical Sciences: X-ray Structure Analysis Online
Dergi ISSN 1348-2238
Makale Dili İngilizce
Basım Tarihi 01-2008
Cilt No 24
Sayı 10
Doi Numarası 10.2116/analscix.24.x253