Crystal structure of tetrakis(alaninato)di(μ)aquadicobalt(II) monohydrate
Yazarlar (4)
Onur Şahin Ondokuz Mayis Üniversitesi, Türkiye
Orhan Büyükgüngör
Ondokuz Mayis Üniversitesi, Türkiye
Ondokuz Mayis Üniversitesi, Türkiye
Dursun Ali Köse Hacettepe Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
| Makale Türü |
Diğer (Teknik, not, yorum, vaka takdimi, editöre mektup, özet, kitap krıtiği,
araştırma notu, bilirkişi raporu ve benzeri)
(SCOPUS dergilerinde yayınlanan teknik not,
editöre mektup, tartışma, vaka takdimi ve özet türünden makale)
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| Dergi Adı | Analytical Sciences X Ray Structure Analysis Online | ||
| Dergi ISSN | 1348-2238 | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2008 |
| Cilt / Sayı / Sayfa | 24 / 11 / – | DOI | 10.2116/analscix.24.x269 |
| Makale Linki | https://www.jstage.jst.go.jp/article/analscix/24/0/24_0_x269/_pdf | ||
| Özet |
| The title compound, tetrakis (alaninato) di (m) aquadicobalt (II) monohydrate, is a three-dimensional hydrogen-bonded supramolecular complex, which crystallizes in the monoclinic space group P21/c with unit-cell parameters a= 13.7266 (7), b= 4.9866 (2), c= 19.4759 (10) Å and Z= 2. The Co (II) ion is in an octahedral coordination environment comprising two amino N atoms, two carboxylate O atoms and two O atoms from water molecules. The molecules are linked principally by N–H· O hydrogen bonds involving the amino NH2 groups and carboxylate O atoms, forming R2 2 (8) and R2 2 (12) rings that link to give a one-dimensional network of molecules. The N–H· O hydrogen bonding is supported by three different O–H· O hydrogen bonds from the water O atoms to either a carboxylate O atom or water O atoms in neighbouring molecules. The combination of the intermolecular N–H· O and O–H· O hydrogen bonds produce R2 2 (4), R2 2 (8), R2 2 (12) and R6 6 (32) rings, which lead to three-dimensional polymeric chains. |
| Anahtar Kelimeler |
BM Sürdürülebilir Kalkınma Amaçları
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| Google Scholar | 4 |