| Yazarlar |
Onur Şahin
Ondokuz Mayis Üniversitesi, Turkey |
|
Orhan Büyükgüngör
Ondokuz Mayis Üniversitesi, Turkey |
|
Dursun Ali Köse
Hacettepe Üniversitesi, Turkey |
Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye |
| Özet |
| The title compound, tetrakis(alaninato)di(μ)aquadicobalt(II)monohydrate, is a three-dimensional hydrogen-bonded supramolecular complex, which crystallizes in the monoclinic space group P21/c with unit-cell parameters a = 13.7266(7), b = 4.9866(2), c = 19.4759(10)Å and Z = 2. The Co(II) ion is in an octahedral coordination environment comprising two amino N atoms, two carboxylate O atoms and two O atoms from water molecules. The molecules are linked principally by N-H···O hydrogen bonds involving the amino NH2 groups and carboxylate O atoms, forming R22(8) and R22(12) rings that link to give a one-dimensional network of molecules. The N-H···O hydrogen bonding is supported by three different O-H···O hydrogen bonds from the water O atoms to either a carboxylate O atom or water O atoms in neighbouring molecules. The combination of the intermolecular N-H·O and O-H···O hydrogen bonds produce R22(4), R22(8), R22(12) and R66(32) rings, which lead to three-dimensional polymeric chains. 2008 © The Japan Society for Analytical Chemistry. |
| Anahtar Kelimeler |
| Makale Türü | Diğer (Teknik, not, yorum, vaka takdimi, editöre mektup, özet, kitap krıtiği, araştırma notu, bilirkişi raporu ve benzeri) |
| Makale Alt Türü | SCOPUS dergilerinde yayımlanan teknik not, editöre mektup, tartışma, vaka takdimi ve özet türünden makale |
| Dergi Adı | Analytical Sciences: X-ray Structure Analysis Online |
| Dergi ISSN | 1348-2238 |
| Makale Dili | İngilizce |
| Basım Tarihi | 01-2008 |
| Cilt No | 24 |
| Sayı | 11 |
| Doi Numarası | 10.2116/analscix.24.x269 |
| Atıf Sayıları | |
| SCOPUS | 3 |
