Syntheses, crystal structures, and DFT calculations of N-(Pyridin-2-ylmethylene)nicotinohydrazide dihydrate and its copper complex
Yazarlar (5)
Dr. Öğr. Üyesi Ömer AYDOĞDU Kafkas Üniversitesi, Türkiye
Doç. Dr. Füreya Elif ÖZTÜRKKAN Kafkas Üniversitesi, Türkiye
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
Hacettepe Üniversitesi, Türkiye
Doç. Dr. Güventürk UĞURLU Kafkas Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of the Iranian Chemical Society (Q3) | ||
| Dergi ISSN | 1735-207X Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2025 |
| Cilt / Sayı / Sayfa | 22 / 4 / 683–697 | DOI | 10.1007/s13738-025-03177-0 |
| Makale Linki | https://doi.org/10.1007/s13738-025-03177-0 | ||
| UAK Araştırma Alanları |
Anorganik Kimya
Spektroskopi
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| Özet |
| A Schiff base ligand, N'-(pyridine-2-ylmethylene)nicotinohydrazide dihydrate (I) and its Cu complex, catena-Poly[N'-(picolinylpyridine-3-carbohydrazonate)copper(II) (II) have been synthesized and their structures have been determined by 1H, 13C NMR and FT-IR spectroscopies, elemental analysis and single crystal X-ray diffraction technique. The SCXRD analysis conforms the I crystallized in a Triclinic crystal system, with a P−1 space group and lattice parameters are α = 87.910 (4)°, β = 76.629 (3)°, γ = 80.769 (3) °. II crystallized in an Orthorhombic crystal system, with a Pbca space group and lattice parameters, are a = 8.6502 (3) Å, b = 11.4314 (4) Å, and c = 25.4146 (6) Å, α, β, γ = 90°. When the FT-IR spectra of the functional groups of the two synthesized compounds were examined, it was determined that the vibrations of the N–N and pyridine C–N groups observed in the spectra of Compound I … |
| Anahtar Kelimeler |
| Cu(II) complex | DFT | N-donor ligand | Nicotinic hydrazide | Schiff base |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 2 |
| Scopus | 2 |
| Google Scholar | 5 |