Adsorption Capacity, Reaction Kinetics and Thermodynamic Studies on Ni(II) Removal with GO@Fe3O4@Pluronic-F68 Nanocomposite
      
Yazarlar (4)
Dr. Öğr. Üyesi Ali ÇİÇEKÇİ Kafkas Üniversitesi, Türkiye
Fatih Sevim Atatürk Üniversitesi, Türkiye
Melike Sevim Atatürk Üniversitesi, Türkiye
Doç. Dr. Erbil KAVCI Kafkas Üniversitesi, Türkiye
Makale Türü Açık Erişim Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Polymers (Q1)
Dergi ISSN 2073-4360 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili Türkçe Basım Tarihi 08-2025
Cilt / Sayı / Sayfa 17 / 15 / – DOI 10.3390/polym17152141
Makale Linki https://doi.org/10.3390/polym17152141
Özet
In recent years, industrial wastewater discharge containing heavy metals has increased significantly and has adversely affected both human health and the aquatic ecosystem. The increasing demand for metals in industry has prompted researchers to focus on developing effective and economical methods for removal of these metals. In this study, the removal of Ni(II) from wastewater using the Graphene oxide@Fe3O4@Pluronic-F68 (GO@Fe3O4@Pluronic-F68) nano composite as an adsorbent was investigated. The nanocomposite was characterised using a series of analytical methods, including Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), X-ray diffraction (XRD), and Brunauer-Emmett-Teller (BET) analysis. The effects of contact time, pH, adsorbent amount, and temperature parameters on adsorption were investigated. Various adsorption isotherm models were applied to interpret the equilibrium data in aqueous solutions; the compatibility of the Langmuir, Freundlich, Temkin, and Dubinin-Radushkevich models with experimental data was examined. For a kinetic model consistent with experimental data, pseudo-first-order, pseudo-second-order, Elovich, and intra-particle diffusion models were examined. The maximum adsorption capacity was calculated as 151.5 mg·g−1 in the Langmuir isotherm model. The most suitable isotherm and kinetic models were the Freundlich and pseudo-second-order kinetic models, respectively. These results demonstrate the potential of the GO@Fe3O4@Pluronic-F68 nanocomposite as an adsorbent offering a sustainable solution for Ni(II) removal.
Anahtar Kelimeler
adsorption capacity | environmental remediation | heavy metal removal | nanocomposite | wastewater treatment