| Yazarlar (6) |
Vijdan Yavuz
Kafkas Üniversitesi, Türkiye |
Doç. Dr. Füreya Elif ÖZTÜRKKAN
Kafkas Üniversitesi, Türkiye |
|
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye |
Doç. Dr. Mustafa SERTÇELİK
Kafkas Üniversitesi, Türkiye |
Doç. Dr. Giray Buğra AKBABA
Kafkas Üniversitesi, Türkiye |
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye |
| Özet |
| Two copper(II) complexes, triaquabis(4-sulfamoylbenzoato-κO1)copper(II) (Complex 1) and aquabis(methyl pyridine-3-carboxylate-κN)bis(4-sulfamoylbenzoato-κO1)copper(II) (Complex 2), were synthesized and characterized by SC-XRD, elemental analysis, FT-IR, and UV–Vis spectroscopy. Crystallographic studies showed that Complex 1 (C₁₄H₁₈CuN₂O₁₁S₂) crystallizes in the orthorhombic system (Cmc2₁, a = 22.66, b = 10.43, c = 8.40 Å), while Complex 2 (C₂₈H₂₈CuN₄O₁₃S₂) adopts a monoclinic system (C2/c, a = 24.79, b = 5.73, c = 23.81 Å, β = 110.7°). Both feature distorted square-pyramidal Cu(II) centers stabilized by hydrogen bonding, as confirmed by Hirshfeld surface analysis. FT-IR spectra showed characteristic metal–ligand vibrations (Cu–O ∼530 cm⁻¹ in both complexes, Cu–N ∼470 cm⁻¹ in Complex 2), while UV–Vis spectra exhibited d–d transitions around 750 … |
| Anahtar Kelimeler |
| 4-sulfamoylbenzoate | Antibacterial activity | Copper(ii) | Methyl pyridine-3-carboxylate | Molecular docking | XRD |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale |
| Dergi Adı | Journal of Molecular Structure |
| Dergi ISSN | 0022-2860 Wos Dergi Scopus Dergi |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Dergi Grubu | Q4 |
| Makale Dili | İngilizce |
| Basım Tarihi | 09-2025 |
| Cilt No | 1350 |
| Sayı | 1 |
| Doi Numarası | 10.1016/j.molstruc.2025.144137 |
| Makale Linki | https://doi.org/10.1016/j.molstruc.2025.144137 |
| Atıf Sayıları |
