Development and characterization of a thiophene-bridged bis-bodipy fluorophore exhibiting π-conjugation and selective Fe³⁺ sensing
Yazarlar (3)
Arş. Gör. Seda Çetindere Gebze Teknik Üniversitesi, Türkiye
Arş. Gör. Gizem Gümüşgöz Çelik Gebze Teknik Üniversitesi, Türkiye
Doç. Dr. Musa ERDOĞAN Kafkas Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Molecular Structure (Q2) | ||
| Dergi ISSN | 0022-2860 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 02-2026 |
| Cilt / Sayı / Sayfa | 1351 / 1 / 144393–0 | DOI | 10.1016/j.molstruc.2025.144393 |
| Makale Linki | https://doi.org/10.1016/j.molstruc.2025.144393 | ||
| UAK Araştırma Alanları |
Organik Kimya
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| Özet |
| A novel π-conjugated fluorescent compound, herein referred to as BisThio-BDPY, incorporating a central thiophene ring substituted at the 3- and 4-positions with para-BODIPY-functionalized phenyl groups was synthesized and fully characterized. The compound exhibited strong absorption and fluorescence attributed to BODIPY units, with photophysical properties evaluated across various solvents. Selective and sensitive fluorescence quenching by Fe3+ ions was demonstrated, outperforming a broad spectrum of competing metal ions. Fluorescence titration showed a linear response between 10 and 60 μM Fe3+, with a detection limit of 0.40 μM, below international permissible levels for drinking water. Job’s plot analysis confirmed a 1:1 stoichiometric interaction between the probe and Fe3+. These results highlight the probe’s potential for environmental Fe3+ monitoring and bioimaging applications. |
| Anahtar Kelimeler |
| Bis-BODIPY | Fe3+ detection | Fluorescence quenching | Fluorescent sensor | Thiophene bridge | Thiophene-BODIPY conjugates | Turn-off | π-Conjugated systems |
Science Direct
Development and characterization of a thiophene-bridged bis-bodipy fluorophore exhibiting π-conjugation and selective Fe³⁺ sensing
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Google Scholar | 1 |