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Development and characterization of a thiophene-bridged bis-bodipy fluorophore exhibiting π-conjugation and selective Fe³⁺ sensing  
Yazarlar (3)
Seda Cetindere
Gebze Teknik Üniversitesi, Türkiye
Gizem Gümüşgöz Çelik
Gebze Teknik Üniversitesi, Türkiye
Doç. Dr. Musa ERDOĞAN Doç. Dr. Musa ERDOĞAN
Kafkas Üniversitesi, Türkiye
Devamını Göster
Özet
A novel π-conjugated fluorescent compound, herein referred to as BisThio-BDPY, incorporating a central thiophene ring substituted at the 3- and 4-positions with para-BODIPY-functionalized phenyl groups was synthesized and fully characterized. The compound exhibited strong absorption and fluorescence attributed to BODIPY units, with photophysical properties evaluated across various solvents. Selective and sensitive fluorescence quenching by Fe3+ ions was demonstrated, outperforming a broad spectrum of competing metal ions. Fluorescence titration showed a linear response between 10 and 60 μM Fe3+, with a detection limit of 0.40 μM, below international permissible levels for drinking water. Job's plot analysis confirmed a 1:1 stoichiometric interaction between the probe and Fe3+. These results highlight the probe's potential for environmental Fe3+ monitoring and bioimaging applications.
Anahtar Kelimeler
Bis-BODIPY | Fe3+ detection | Fluorescence quenching | Fluorescent sensor | Thiophene bridge | Thiophene-BODIPY conjugates | Turn-off | π-Conjugated systems
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale
Dergi Adı Journal of Molecular Structure
Dergi ISSN 0022-2860 Wos Dergi Scopus Dergi
Dergi Grubu Q2
Makale Dili İngilizce
Basım Tarihi 02-2026
Cilt No 1351
Sayı 1
Doi Numarası 10.1016/j.molstruc.2025.144393