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Synthesis, structure, and properties of a polymeric copper(II) complex with anion of maleic acid   
Yazarlar (8)
Esmira Arif Aga Guliyeva
Ajdar Akper Mejidov
Rayyat Huseyn Ismayilov
Malahat Bagiyeva Rustam
Bahattin Yalcin
Doç. Dr. Füreya Elif ÖZTÜRKKAN Doç. Dr. Füreya Elif ÖZTÜRKKAN
Kafkas Üniversitesi, Türkiye
Onur Sahin
Mahammad Allahverdi Bayramov
Devamını Göster
Özet
A new polymeric copper(II)–maleato complex, used as a dicarboxylate ligand, was synthesized {Na2[Cu(C4H2O4)2]·2H2O}n (1). The resulting complex was characterized by elemental analysis, infrared and UV–visible spectroscopy, and X-ray crystallography. Spectroscopic data indicate that the maleato ion coordinates in a chelating bidentate mode, creating a distorted square planar coordination environment around Cu(II). X-ray crystallography confirmed the formulation (1) and revealed that the central Cu(II) ion is in a distorted square planar. The maleato ion acts as a bidentate chelator, coordinating through two carboxylate oxygens to form a stable four-membered ring. This study extends our understanding of the coordination behavior of π-conjugated dicarboxylic acids with transition-metal ions. Molecular docking studies demonstrated that the polymeric copper(II)–maleic acid complex exhibited strong binding …
Anahtar Kelimeler
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale
Dergi Adı TRANSITION METAL CHEMISTRY
Dergi ISSN 0340-4285 Wos Dergi Scopus Dergi
Dergi Grubu Q3
Makale Dili İngilizce
Basım Tarihi 12-2025
Cilt No 51
Sayı 1
DOI Numarası 10.1007/s11243-025-00705-y
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
Synthesis, structure, and properties of a polymeric copper(II) complex with anion of maleic acid

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