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Doç. Dr. Füreya Elif ÖZTÜRKKAN
Kafkas Üniversitesi, Türkiye |
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| Özet |
| A new polymeric copper(II)–maleato complex, used as a dicarboxylate ligand, was synthesized {Na2[Cu(C4H2O4)2]·2H2O}n (1). The resulting complex was characterized by elemental analysis, infrared and UV–visible spectroscopy, and X-ray crystallography. Spectroscopic data indicate that the maleato ion coordinates in a chelating bidentate mode, creating a distorted square planar coordination environment around Cu(II). X-ray crystallography confirmed the formulation (1) and revealed that the central Cu(II) ion is in a distorted square planar. The maleato ion acts as a bidentate chelator, coordinating through two carboxylate oxygens to form a stable four-membered ring. This study extends our understanding of the coordination behavior of π-conjugated dicarboxylic acids with transition-metal ions. Molecular docking studies demonstrated that the polymeric copper(II)–maleic acid complex exhibited strong binding … |
| Anahtar Kelimeler |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale |
| Dergi Adı | TRANSITION METAL CHEMISTRY |
| Dergi ISSN | 0340-4285 Wos Dergi Scopus Dergi |
| Dergi Grubu | Q3 |
| Makale Dili | İngilizce |
| Basım Tarihi | 12-2025 |
| Cilt No | 51 |
| Sayı | 1 |
| DOI Numarası | 10.1007/s11243-025-00705-y |