Diaqua(isonicotinamide-κN1)(4-methoxybenzoato-κ2O,O′)(4-methoxybenzoato-κO)cobalt(II)

Hokelek, Tuncer; Suzen, Yasemin; Tercan, Baris; Tenlik, Erdinc; NECEFOĞLU, HACALİ

doi:10.1107/S160053681002194X

Diaqua(isonicotinamide-κN¹)(4-methoxybenzoato-κ²O,O′)(4-methoxybenzoato-κO)cobalt(II)

Yazarlar (5)

Tuncer Hokelek
Hacettepe Üniversitesi, Türkiye

Yasemin Suzen
Anadolu Üniversitesi, Türkiye

Baris Tercan
Karabük Üniversitesi, Türkiye

Erdinc Tenlik
Kafkas Üniversitesi, Türkiye

Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye

Makale Türü	Özgün Makale (ESCI dergilerinde yayınlanan tam makale)
Dergi Adı	Acta Crystallographica Section E Structure Reports Online
Dergi ISSN	1600-5368
Makale Dili	İngilizce	Basım Tarihi	07-2010
Cilt / Sayı / Sayfa	66 / 7 / –	DOI	10.1107/S160053681002194X
Makale Linki	https://publons.com/wos-op/publon/10820046/
UAK Araştırma Alanları	Fen Bilimleri ve Matematik

Özet

In the title complex, [Co(C8H7O3) 2(C6H6N2O)(H2O) 2], the Co^II atom is coordinated by three O atoms from two 4-methoxy-benzoate ligands, which act in different modes, viz. monodentate and bidentate, two water molecules and one N atom of the isonicotinamide ligand in a distorted octa-hedral geometry. The monodentate-coordinated carboxylate group is involved in an intra-molecular O-H⋯O hydrogen bond with the coordinated water molecule. In the crystal structure, inter-molecular O-H⋯O and N-H⋯O hydrogen bonds link the molecules into layers parallel to the ab plane. The crystal packing is further stabilized by weak C-H⋯O hydrogen bonds and π-π inter-actions indicated by the short distance of 3.6181 (8) Å between the centroids of the benzene and pyridine rings of neighbouring molecules.

Anahtar Kelimeler

Science Direct

BM Sürdürülebilir Kalkınma Amaçları

Atıf Sayıları

Diaqua(isonicotinamide-κN¹)(4-methoxybenzoato-κ²O,O′)(4-methoxybenzoato-κO)cobalt(II)

Diaqua(isonicotinamide-κN1)(4-methoxybenzoato-κ2O,O′)(4-methoxybenzoato-κO)cobalt(II)

Paylaş

Diaqua(isonicotinamide-κN¹)(4-methoxybenzoato-κ²O,O′)(4-methoxybenzoato-κO)cobalt(II)