The superiority of the classical synthesis compared to the hydrothermal synthesis upon the structural, optical absorption and fluorescent properties of new Cd (II) 3 …
Yazarlar (5)
Doç. Dr. Füreya Elif ÖZTÜRKKAN Türkiye
Mustafa Sertçelik
Mustafa Yüksek
Ayhan Elmalı
Prof. Dr. Ertan Şahin Kafkas Üniversitesi
| Makale Türü | Özgün Makale (Uluslararası alan indekslerindeki dergilerde yayınlanan tam makale) | ||
| Dergi Adı | Inorganica Chimica Acta | ||
| Makale Dili | – | Basım Tarihi | 09-2020 |
| Cilt / Sayı / Sayfa | 509 / 0 / 119694–0 | DOI | – |
| Makale Linki | https://www.sciencedirect.com/science/article/pii/S0020169320304163 | ||
| UAK Araştırma Alanları |
Anorganik Kimya
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| Özet |
| Three new cadmium–3-fluorobenzoate complexes with pyridine-3-carboxamide/pyridine-3-carboxylate complexes, namely, [Cd2(C7H4FO2)4(C6H6N2O)2(H2O)2] (1), [Cd2(C7H4FO2)4(C6H6N2O)2(H2O)2] (2), [Cd(C7H4FO2)(C6H4NO2)(H2O)] (3) were obtained under classical and two different hydrothermal conditions, respectively. The structures of all prepared complexes were characterized by elemental analysis, FT-IR and 1H NMR spectroscopy, TGA/DTA and single crystal X-ray analyses. In addition, the structural features of the complexes were studied theoretically by Hirshfeld surface analysis and the X-ray diffraction analyses were supported. It was determined that the carboxylate groups of 3-fluorobenzoate and pyridine-3-carboxylate behaved as chelating bidentate ligands. Hirshfeld surface analysis indicated that H⋯H, H⋯O/O⋯H, H⋯C/C⋯H, H⋯F/F⋯H and C⋯C interactions are the significant … |
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