Diaquabis (N, N-diethylnicotinamide-κN1) bis (4-ethylbenzoato-κO) cobalt (II)
Yazarlar (5)
Hacali Necefoğlu
Ali Maracı
Doç. Dr. Vedat ADIGÜZEL Türkiye
Baris Tercan
Tuncer Hökelek Kafkas Üniversitesi
| Makale Türü | Özgün Makale (Uluslararası alan indekslerindeki dergilerde yayınlanan tam makale) | ||
| Dergi Adı | Structure Reports | ||
| Makale Dili | – | Basım Tarihi | 05-2011 |
| Cilt / Sayı / Sayfa | 67 / 5 / – | DOI | – |
| Makale Linki | https://journals.iucr.org/paper?SU2268 | ||
| UAK Araştırma Alanları |
Fiziksel Kimya
|
||
| Özet |
| The title CoII complex, [Co(C9H9O2)2(C10H14N2O)2(H2O)2], contains two 4-ethylbenzoate (PEB), two monodentate diethylnicotinamide (DENA) ligands and two water molecules. The four O atoms in the equatorial plane around the CoII ion form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two N atoms of the DENA ligands in the axial positions. Intramolecular O—H⋯O hydrogen bonds link the water molecules to the carboxylate groups. The dihedral angles between the carboxylate groups and the adjacent benzene rings are 4.52 (18) and 4.56 (18)°, while the pyridine rings and the benzene rings are oriented at dihedral angles of 7.76 (10) and 5.67 (13)°. In the crystal, intermolecular O—H⋯O hydrogen bonds link the molecules into chains propagating along [010]. C—H⋯O interactions and a π–π contact between the pyridine rings … |
| Anahtar Kelimeler |
