Generation of singlet oxygen (O-1(2)) from hydrogen peroxide decomposition by in situ generated hypervalent iodoarene reagents

KALAY, ERBAY; Kılıç, Hamdullah; Catir, Mustafa; Cakici, Murat; Kazaz, Cavit

doi:10.1515/pac-2013-0812

Generation of singlet oxygen (O-1(2)) from hydrogen peroxide decomposition by in situ generated hypervalent iodoarene reagents

Yazarlar (5)
Doç. Dr. Erbay KALAY Kurum Bilgileri Kars Meslek Yüksekokulu Malzeme ve Malzeme İşleme Teknolojileri Polimer Teknolojisi Özgeçmiş Sayfası İletişim Bilgileri: Kafkas Üniversitesi, Türkiye
Hamdullah Kılıç Atatürk Üniversitesi, Türkiye
Mustafa Catir Türkiye
Murat Cakici Türkiye
Cavit Kazaz Atatürk Üniversitesi, Türkiye

Devamını Göster

Özet

AbstractA novel method for the production of singlet oxygen from H2O2 was developed. A combination of iodoarene (ArI), methyltrioxorhenium (MTO), and H2O2 in the presence of pyridine as the co-catalyst efficiently produced singlet molecular oxygen (1O2) under biphasic conditions. The existence of 1O2 was demonstrated by trapping experiments with aromatic dienes, 1,3-cyclodienes, and alkenes. The mechanism of 1O2 production from the iodoarene/MTO/35 % H2O2 system and the reaction scope was also discussed.

Anahtar Kelimeler

Makale Türü	Özgün Makale
Makale Alt Türü	SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale
Dergi Adı	PURE AND APPLIED CHEMISTRY
Dergi ISSN	0033-4545 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler	SCI-Expanded
Dergi Grubu	Q3
Makale Dili	İngilizce
Basım Tarihi	06-2014
Cilt No	86
Sayı	6
Sayfalar	945 / 952
Doi Numarası	10.1515/pac-2013-0812
Makale Linki	https://www.degruyter.com/document/doi/10.1515/pac-2013-0812/html

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Atıf Sayıları
WoS	10

Generation of singlet oxygen (O-1(2)) from hydrogen peroxide decomposition by in situ generated hypervalent iodoarene reagents

Akademisyenler > Erbay KALAY > Yayın Detayı

Generation of singlet oxygen (O-1(2)) from hydrogen peroxide decomposition by in situ generated hypervalent iodoarene reagents

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