Generation of singlet oxygen (O-1(2)) from hydrogen peroxide decomposition by in situ generated hypervalent iodoarene reagents

KALAY, ERBAY; Kılıç, Hamdullah; Catir, Mustafa; Cakici, Murat; Kazaz, Cavit

doi:10.1515/pac-2013-0812

Generation of singlet oxygen (O-1(2)) from hydrogen peroxide decomposition by in situ generated hypervalent iodoarene reagents

Yazarlar (5)

Doç. Dr. Erbay KALAY Kafkas Üniversitesi, Türkiye

Hamdullah Kılıç Atatürk Üniversitesi, Türkiye

Mustafa Catir Türkiye

Murat Cakici Türkiye

Cavit Kazaz Atatürk Üniversitesi, Türkiye

Makale Türü	Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı	PURE AND APPLIED CHEMISTRY (Q3)
Dergi ISSN	0033-4545 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler	SCI-Expanded
Makale Dili	İngilizce	Basım Tarihi	06-2014
Cilt / Sayı / Sayfa	86 / 6 / 945–952	DOI	10.1515/pac-2013-0812
Makale Linki	https://www.degruyter.com/document/doi/10.1515/pac-2013-0812/pdf

Özet

AbstractA novel method for the production of singlet oxygen from H2O2 was developed. A combination of iodoarene (ArI), methyltrioxorhenium (MTO), and H2O2 in the presence of pyridine as the co-catalyst efficiently produced singlet molecular oxygen (1O2) under biphasic conditions. The existence of 1O2 was demonstrated by trapping experiments with aromatic dienes, 1,3-cyclodienes, and alkenes. The mechanism of 1O2 production from the iodoarene/MTO/35 % H2O2 system and the reaction scope was also discussed.

Anahtar Kelimeler

BM Sürdürülebilir Kalkınma Amaçları

Atıf Sayıları
WoS	11

Generation of singlet oxygen (O-1(2)) from hydrogen peroxide decomposition by in situ generated hypervalent iodoarene reagents

Dergi Adı	PURE AND APPLIED CHEMISTRY
Yayıncı	Walter de Gruyter GmbH
Açık Erişim	Hayır
ISSN	0033-4545
E-ISSN	1365-3075
CiteScore	3,2
SJR	0,426
SNIP	0,830

Generation of singlet oxygen (O-1(2)) from hydrogen peroxide decomposition by in situ generated hypervalent iodoarene reagents

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