Tuning the optoelectronic properties of iminodibenzyl–triphenylamine based semiconductors: hybrid self-powered photodetector applications
Yazarlar (4)
Doç. Dr. Musa ERDOĞAN Kafkas Üniversitesi, Türkiye
Hilal Medetalibeyoğlu Kafkas Üniversitesi, Türkiye
Fatma Yıldırım Atatürk Üniversitesi, Türkiye
Şakir Aydoğan Atatürk Üniversitesi, Türkiye
Makale Türü Açık Erişim Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Journal of Materials Chemistry C (Q1)
Dergi ISSN 2050-7526 Dergi Bilgileri (2026)
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 01-2026
Cilt / Sayı / Sayfa 14 / 26 / 11684–11700 DOI 10.1039/d6tc00959j
Makale Linki https://doi.org/10.1039/d6tc00959j
UAK Araştırma Alanları
Organik Kimya
Özet
Here, electron-rich organic semiconductors (IDB-TPA 1 and IDB-TPA 2) were designed by integrating the iminodibenzyl (ID) core with triphenylamine (TPA) units to achieve efficient charge distribution and tunable optoelectronic properties. The compounds were synthesized starting from iminodibenzyl core via successive bromination, N-alkylation, and Suzuki coupling reactions, and their structures were characterized by 1H NMR, 13C NMR, FTIR, and mass spectrometry. In addition, a comprehensive theoretical investigation of the IDB-TPA derivatives was performed using DFT and TD-DFT methods to elucidate their electronic structures and excited-state behavior. Furthermore, ıt was examined the performance of hybrid heterojunction (HJ) self-driven photodetectors based on IDB–TPA 1/n-Si and IDB–TPA 2/n-Si (referred to as D1 and D2, respectively). Beyond varying white light intensities (10–150 mW/cm²), the …
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