Synthesis of gold nanoparticles on diazonium-generated heteroaryl films and their electrocatalytic activities
Yazarlar (3)
Ömer Faruk Ünal
Ağrı İbrahim Çeçen Üniversitesi, Türkiye
Doç. Dr. Ali YEŞİLDAĞ Kafkas Üniversitesi, Türkiye
Prof. Dr. Duygu Ekinci Atatürk Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Electrochimica Acta (Q1)
Dergi ISSN 0013-4686 Dergi Bilgileri (2018)
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 11-2018
Cilt / Sayı / Sayfa 290 / 1 / 474–486 DOI 10.1016/j.electacta.2018.09.083
Makale Linki https://linkinghub.elsevier.com/retrieve/pii/S0013468618320693
UAK Araştırma Alanları
Analitik Kimya
Özet
In this paper, a novel electrochemical sensing platform has been developed based on the electrodes modified with heteroaromatic molecules decorated with gold nanoparticles (AuNPs). For this purpose, the GC electrodes were first covered with pyridine and phenanthroline rings by using diazonium reduction method. Then, the formation of AuNPs was achieved via the electrochemical reduction of AuCl4− ions preadsorbed to the modified GC surfaces. The AuNPs, for comparison, were also prepared on polyphenylene films (PPh) obtained by electrochemical reduction of in situ generated benzenediazonium salts. The existence of the nanoparticles was confirmed by using spectroscopic and electrochemical techniques such as scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and cyclic voltammetry. The results have shown that the homogeneity of particle …
Anahtar Kelimeler
Diazonium modification method | Electrochemical catalysis | Gold nanoparticles | Heteroaromatic films | Hydrazine hydrate | Nitrobenzene