Yazarlar |
Füreya Elif ÖZTÜRKKAN
Kafkas Üniversitesi, Türkiye |
Mustafa Yüksek
Kafkas Üniversitesi, Türkiye |
Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye |
Özet |
Two mixed complexes diaquabis(2-bromobenzoato-κO)bis-(N,N-diethylnicotinamide-κN')cobalt(II) [Co(C7H4BrO2)2(C10H14N2O)(H2O)2] (Complex I) and diaquabis(2-bromobenzoato-κO)bis-(N,N-diethylnicotinamide-κN')nickel(II) [Ni(C7H4BrO2)2(C10H14N2O)(H2O)2] (Complex II) have been synthesized and characterized by elemental analysis, TG/DTA, FT-IR spectra and X-ray powder diffraction(XRPD). In addition, the optical absorption and emission properties of metal-organic complexes were investigated by using UV-vis absorption and fluorescence spectrophotometers, respectively. Complex I showed larger absorption and emission intensities than complex II in the visible region. This behavior was attributed to the numbers of π → π∗ transitions which are take place in the visible region. |
Anahtar Kelimeler |
Co(II) | Ni(II) | Bromobenzoates | Absorption | Fluorescence |
Makale Türü | Özgün Makale |
Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale |
Dergi Adı | OPTIK |
Dergi ISSN | 0030-4026 |
Dergi Tarandığı Indeksler | SCI |
Makale Dili | İngilizce |
Basım Tarihi | 01-2016 |
Cilt No | 127 |
Sayı | 19 |
Sayfalar | 7710 / 7716 |
Doi Numarası | 10.1016/j.ijleo.2016.05.138 |
Makale Linki | http://linkinghub.elsevier.com/retrieve/pii/S0030402616305915 |