Synthesis spectroscopic and fluorescence properties of N N diethylnicotinamide adducts of 2 bromobenzoate Co II and Ni II metal organic complexes
Yazarlar (3)
Doç. Dr. Füreya Elif ÖZTÜRKKAN
Kafkas Üniversitesi, Türkiye
Mustafa Yüksek
Kafkas Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Optik (Q4) | ||
| Dergi ISSN | 0030-4026 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 10-2016 |
| Cilt / Sayı / Sayfa | 127 / 19 / 7710–7716 | DOI | 10.1016/j.ijleo.2016.05.138 |
| Makale Linki | http://linkinghub.elsevier.com/retrieve/pii/S0030402616305915 | ||
| Özet |
| Two mixed complexes diaquabis(2-bromobenzoato-κO)bis-(N,N-diethylnicotinamide-κN')cobalt(II) [Co(C7H4BrO2)2(C10H14N2O)(H2O)2] (Complex I) and diaquabis(2-bromobenzoato-κO)bis-(N,N-diethylnicotinamide-κN')nickel(II) [Ni(C7H4BrO2)2(C10H14N2O)(H2O)2] (Complex II) have been synthesized and characterized by elemental analysis, TG/DTA, FT-IR spectra and X-ray powder diffraction(XRPD). In addition, the optical absorption and emission properties of metal-organic complexes were investigated by using UV-vis absorption and fluorescence spectrophotometers, respectively. Complex I showed larger absorption and emission intensities than complex II in the visible region. This behavior was attributed to the numbers of π → π∗ transitions which are take place in the visible region. |
| Anahtar Kelimeler |
| Co(II) | Ni(II) | Bromobenzoates | Absorption | Fluorescence |