Two new potential optical materials: Co(II) and Ni(II) 3-fluorobenzoate complexes with pyridine-3-carboxamide
Yazarlar (6)
Doç. Dr. Füreya Elif ÖZTÜRKKAN
Kafkas Üniversitesi, Türkiye
Doç. Dr. Mustafa SERTÇELİK
Kafkas Üniversitesi, Türkiye
Mustafa Yüksek
Kafkas Üniversitesi, Türkiye
Betül Küçüköz
Ankara Üniversitesi, Türkiye
Ayhan Elmali
Ankara Üniversitesi, Türkiye
Ertan Şahin
Atatürk Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Coordination Chemistry (Q3) | ||
| Dergi ISSN | 0095-8972 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 03-2019 |
| Cilt / Sayı / Sayfa | 72 / 5 / 786–795 | DOI | 10.1080/00958972.2019.1590560 |
| Makale Linki | https://www.tandfonline.com/doi/full/10.1080/00958972.2019.1590560 | ||
| Özet |
| Two new complexes, [Co(3-fba) 2 (na) 2 (H 2 O) 2 ] (1) and [Ni(3-fba) 2 (na) 2 (H 2 O) 2 ] (2) (where 3-fba = 3-fluorobenzoate and na = pyridine-3-carboxamide, nicotinamide), were synthesized and characterized using different techniques (elemental analysis, FT-IR, UV-Vis spectrophotometer, single-crystal X-ray diffraction, fluorescence spectroscopy, and TGA/DTA analysis). X-ray structural analysis revealed that 1 and 2 are isostructural and exhibit distorted octahedral coordination geometry. In each molecule, metal atoms (Co +2 and Ni +2 ) are linked by two 3-fluorobenzoate anions, two pyridine-3-carboxamide ligands, and two water molecules per formula unit. The 3-fluorobenzoate and pyridine-3-carboxamide are monodentate through a carboxylate oxygen atom and the nitrogen atom of the pyridine ring, respectively. UV-Vis results showed that the studied complexes have absorption edges similar to semiconductor structures. Namely, 1 and 2 indicated emission behaviors around 370 nm and 361 nm, respectively. |
| Anahtar Kelimeler |
| 3-Fluorobenzoic acid | hydrothermal synthesis | linear absorption | fluorescence | XRD |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| WoS | 6 |
| SCOPUS | 6 |
| Google Scholar | 10 |