| Yazarlar |
Doç. Dr. Füreya Elif ÖZTÜRKKAN
Kafkas Üniversitesi, Türkiye |
Doç. Dr. Mustafa SERTÇELİK
Kafkas Üniversitesi, Türkiye |
Mustafa Yüksek
Kafkas Üniversitesi, Türkiye |
|
Küçüköz Betül
Türkiye |
|
Ayhan Elmalı
Ankara Üniversitesi, Türkiye |
|
Ertan Şahin
Atatürk Üniversitesi, Türkiye |
| Özet |
| Two new complexes, [Co(3-fba) 2 (na) 2 (H 2 O) 2 ] (1) and [Ni(3-fba) 2 (na) 2 (H 2 O) 2 ] (2) (where 3-fba = 3-fluorobenzoate and na = pyridine-3-carboxamide, nicotinamide), were synthesized and characterized using different techniques (elemental analysis, FT-IR, UV-Vis spectrophotometer, single-crystal X-ray diffraction, fluorescence spectroscopy, and TGA/DTA analysis). X-ray structural analysis revealed that 1 and 2 are isostructural and exhibit distorted octahedral coordination geometry. In each molecule, metal atoms (Co +2 and Ni +2 ) are linked by two 3-fluorobenzoate anions, two pyridine-3-carboxamide ligands, and two water molecules per formula unit. The 3-fluorobenzoate and pyridine-3-carboxamide are monodentate through a carboxylate oxygen atom and the nitrogen atom of the pyridine ring, respectively. UV-Vis results showed that the studied complexes have absorption edges similar to semiconductor structures. Namely, 1 and 2 indicated emission behaviors around 370 nm and 361 nm, respectively. |
| Anahtar Kelimeler |
| 3-Fluorobenzoic acid | hydrothermal synthesis | linear absorption | fluorescence | XRD |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale |
| Dergi Adı | JOURNAL OF COORDINATION CHEMISTRY |
| Dergi ISSN | 0095-8972 |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Dergi Grubu | Q3 |
| Makale Dili | İngilizce |
| Basım Tarihi | 04-2019 |
| Cilt No | 72 |
| Sayı | 5 |
| Sayfalar | 786 / 795 |
| Doi Numarası | 10.1080/00958972.2019.1590560 |
| Makale Linki | https://www.tandfonline.com/doi/full/10.1080/00958972.2019.1590560 |
| Atıf Sayıları | |
| WoS | 6 |
| SCOPUS | 6 |
| Google Scholar | 11 |
