Dimeric complexes of copper (II) arylcarboxylate with 4-cyanopyridine: synthesis, structural characterization and linear absorption properties
Yazarlar (1)
Doç. Dr. Füreya Elif ÖZTÜRKKAN Kafkas Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Chemical Sciences (Q4) | ||
| Dergi ISSN | 0974-3626 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 04-2020 |
| Kabul Tarihi | 24-12-2019 | Yayınlanma Tarihi | 11-04-2020 |
| Cilt / Sayı / Sayfa | 132 / 1 / 1–10 | DOI | 10.1007/s12039-020-01765-6 |
| Makale Linki | http://link.springer.com/10.1007/s12039-020-01765-6 | ||
| UAK Araştırma Alanları |
Anorganik Kimya
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| Özet |
| Two new dimeric copper (II) complexes containing 2-chlorobenzoato/4-formylbenzoato and 4-cyanopyridine ligands, [Cu2(μ2-O2CC6H4-Cl)4(C5H4N-CN)2] (1) and [Cu2(μ2-O2CC6H4-CHO)4(C5H4N-CN)4] (2), were synthesized and characterized by elemental analysis, FT-IR and ESR spectroscopy and single-crystal X-ray diffraction methods. In the structure of 1, each copperII cation was surrounded by four oxygen atoms from four different carboxylate of four 2-chlorobenzoate molecules and one nitrogen atom of one 4-cyanopyridine ligand. In the crystal structure of 2, each copperII cation was coordinated by four oxygen atoms from one chelating and two bridging 4-formylbenzoate anions and two nitrogen atoms of two 4-cyanopyridine ligands. C–H···O and C–H···Cl hydrogen bonds (for 1) and C–H···O hydrogen bonds and weak C–H···π interactions (for 2) further stabilize the crystal structures. The linear optical … |
| Anahtar Kelimeler |
| copper (II) | Dimeric complex | linear absorption | paddle-wheel |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 2 |
| Scopus | 2 |
| Google Scholar | 1 |