Di nicotinamide k 2 N 1 O k 2 O N 1 bis aqua bis 4 bromo benzoato kO k 2 O O manganese II
Yazarlar (5)
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye
Doç. Dr. Füreya Elif ÖZTÜRKKAN
Kafkas Üniversitesi, Türkiye
Vijdan Öztürk
Kafkas Üniversitesi, Türkiye
Vedat Adgüzel
Kafkas Üniversitesi, Türkiye
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
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| Dergi Adı | Acta Crystallographica Section E Structure Reports Online (Q4) | ||
| Dergi ISSN | 1600-5368 | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 08-2011 |
| Cilt / Sayı / Sayfa | 67 / 8 / – | DOI | 10.1107/S1600536811028492 |
| Makale Linki | https://doi.org/10.1107/s1600536811028492 | ||
| Özet |
| In the centrosymmetric dinuclear title compound, [Mn 2(C 7H 4BrO 2) 4(C 6H 6N 2O) 2(H 2O) 2], the Mn II atom is coordinated by one N atom from one bridging nicotinamide ligand and one O atom from another symmetry-related bridging nicotinamide ligand, three O atoms from two 4-bromo-benzoate ligands and one water molecule in a distorted octa-hedral geometry. The dihedral angles between the carboxyl-ate groups and the adjacent benzene rings are 10.89 (16) and 8.4 (2)°, while the benzene rings are oriented at a dihedral angle of 6.09 (13)°. Inter-molecular O - H⋯O, N - H⋯O and weak C - H⋯O hydrogen bonds link the molecules into a three-dimensional network. π-π interactions, indicated by short centroid-centroid distances [3.845 (2) Å between the benzene rings, 3.650 (2) Å between the pyridine rings and 3.700 (3) Å between the benzene and pyridine rings] further stabilize the structure. |
| Anahtar Kelimeler |
| data-to-parameter ratio = 18.2 | mean σ(CC) = 0.006 Å | R factor = 0.049 | single-crystal X-ray study | T = 294 K | wR factor = 0.126 |
Science Direct
Di nicotinamide k 2 N 1 O k 2 O N 1 bis aqua bis 4 bromo benzoato kO k 2 O O manganese II
BM Sürdürülebilir Kalkınma Amaçları
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| WoS | 2 |
| SCOPUS | 2 |
| Google Scholar | 6 |
| Google Scholar | 6 |