Aquabis 4 fluorobenzoato O bis nicotinamide N 1 copper II nicotinamide hemisolvate trihydrate
Yazarlar (5)
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye
Doç. Dr. Füreya Elif ÖZTÜRKKAN
Kafkas Üniversitesi, Türkiye
Vijdan Öztürk
Kafkas Üniversitesi, Türkiye
Doç. Dr. Vedat ADIGÜZEL
Kafkas Üniversitesi, Türkiye
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
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| Dergi Adı | Acta Crystallographica Section E Structure Reports Online (Q4) | ||
| Dergi ISSN | 1600-5368 | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2012 |
| Cilt / Sayı / Sayfa | 68 / 1 / – | DOI | 10.1107/S1600536811053116 |
| Makale Linki | https://doi.org/10.1107/s1600536811053116 | ||
| Özet |
| The asymmetric unit of the title compound, [Cu(C 7H 4FO 2) 2-(C 6H 6N 2O) 2(H 2O)]·0.5C 6H 6N 2O·3H 2O, contains two aquabis(4-fluorobenzoato)bis(nicotinamide)copper(II) molecules, one nicotinamide solvent molecule and six water molecules. The Cu II ion is coordinated by two O atoms from two 4-fluorobenzoate ligands, two N atoms from two nicotinamide ligands and one water O atom in a distorted square-pyramidal geometry. In the crystal, O-H···O, O- H···N and N-H···O hydrogen bonds consolidate the crystal packing, which also exhibits π-π interactions between the aromatic rings [centroid-centroid distances 3.692(2)-3.794(2) Å]. |
| Anahtar Kelimeler |
| Data-to-parameter ratio = 16.9 | Mean σ(C-C) = 0.006 Å | R factor = 0.063 | Single-crystal X-ray study | T = 100 K | wR factor = 0.160 |