Diaquabis 4 bromobenzoato O bis N N diethylnicotinamide N 1 copper II
Yazarlar (5)
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
Doç. Dr. Füreya Elif ÖZTÜRKKAN Kafkas Üniversitesi, Türkiye
Vijdan Ozturk
Kafkas Üniversitesi, Türkiye
Kafkas Üniversitesi, Türkiye
Doç. Dr. Vedat ADIGÜZEL Kafkas Üniversitesi, Türkiye
Tuncer Hokelek
Hacettepe Üniversitesi, Türkiye
Hacettepe Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
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| Dergi Adı | Acta Crystallographica Section E Structure Reports Online (Q4) | ||
| Dergi ISSN | 1600-5368 Dergi Bilgileri (2011) | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 09-2011 |
| Kabul Tarihi | 24-08-2011 | Yayınlanma Tarihi | 31-08-2011 |
| Cilt / Sayı / Sayfa | 67 / 9 / – | DOI | 10.1107/S1600536811034787 |
| Makale Linki | http://scripts.iucr.org/cgi-bin/paper?S1600536811034787 | ||
| UAK Araştırma Alanları |
Anorganik Kimya
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| Özet |
| The title CuII complex, [Cu(C7H4BrO2)2(C10H14N2O)2(H2O)2], contains two 4-bromobenzoate (PBB), two diethylnicotinamide (DENA) monodentate ligands and two water molecules. The four O atoms in the equatorial plane around the CuII ion form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by two N atoms of the DENA ligands in the axial positions. Intramolecular O—H⋯O hydrogen bonds link the water molecules to the carboxylate groups. The dihedral angles between the carboxylate groups and the adjacent benzene rings are 3.1 (3) and 3.74 (17)°, while the pyridine rings and the benzene rings are oriented at dihedral angles of 6.81 (10) and 3.38 (12)°. In the crystal, intermolecular O—H⋯O hydrogen bonds link the molecules into double chains along the b axis. C—H⋯O interactions are also observed. π–π contacts between pyridine … |
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