Diaqua bis 4 bromo benzoato O bis nicotinamide N 1 copper II
      
Yazarlar (5)
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
Doç. Dr. Füreya Elif ÖZTÜRKKAN Kafkas Üniversitesi, Türkiye
Vijdan Ztürk Kafkas Üniversitesi, Türkiye
Bar Tercan Karabük Üniversitesi, Türkiye
Tuncer Hökelek Hacettepe Üniversitesi, Türkiye
Makale Türü Açık Erişim Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Acta Crystallographica Section E Structure Reports Online (Q4)
Dergi ISSN 1600-5368
Dergi Tarandığı Indeksler SCI
Makale Dili İngilizce Basım Tarihi 07-2011
Cilt / Sayı / Sayfa 67 / 7 / – DOI 10.1107/S1600536811021696
Makale Linki https://journals.iucr.org/e/issues/2011/07/00/su2279/su2279.pdf
Özet
The asymmetric unit of the title mononuclear Cu II complex, [Cu(C 7H 4BrO 2) 2(C 6H 6N 2O) 2(H 2O) 2], contains one half-mol-ecule, the Cu II atom being located on an inversion center. The unit cell contains two nicotinamide (NA), two 4-bromo-benzoate (PBB) ligands and two coordinated water mol-ecules. The four O atoms in the equatorial plane around the Cu II ion form a slightly distorted square-planar arrangement, while the slightly distorted octa-hedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxyl-ate group and the adjacent benzene ring is 22.17 (16)°, while the pyridine ring and the benzene ring are oriented at a dihedral angle of 82.80 (6)°. In the crystal, N - H⋯O, O - H⋯O and C - H⋯O hydrogen bonds link the mol-ecules into a three-dimensional network. A weak C - H⋯π inter-action is also observed. © Necefoǧlu et al. 2011.
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