| Yazarlar |
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye |
Doç. Dr. Füreya Elif ÖZTÜRKKAN
Kafkas Üniversitesi, Türkiye |
Vijdan Öztürk
Türkiye |
Doç. Dr. Vedat ADIGÜZEL
Kafkas Üniversitesi, Türkiye |
|
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye |
| Özet |
| The asymmetric unit of the title mononuclear Cu II complex, [Cu(C 7H 4FO 2) 2(C 10H 14N 2O) 2(H 2O) 2], contains one-half of the molecule. The Cu II ion is located on an inversion centre, and is coordinated by two N atoms from two diethyl-nicotinamide ligands, two O atoms from two 4-fluoro-benzoate (PFB) ligands and two water molecules in a distorted octa-hedral geometry. In the PFB ligand, the carboxylate group is twisted at an angle of 2.10 (14)° from the attached benzene ring. In the crystal structure, Intermolecular O - H⋯O hydrogen bonds link molecules related by translation along the a axis into chains. Weak Intermolecular C - H⋯O hydrogen bonds and π-π interactions between the pyridine rings of neighbouring molecules [centroid-to-centroid distance = 3.571 (2) Å] further consolidate the crystal packing. |
| Anahtar Kelimeler |
| data-to-parameter ratio = 17.6 | mean σ(CC) = 0.002 Å | R factor = 0.033 | single-crystal X-ray study | T = 100 K | wR factor = 0.099 |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale |
| Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS |
| Dergi ISSN | 2056-9890 |
| Dergi Tarandığı Indeksler | SCI |
| Makale Dili | İngilizce |
| Basım Tarihi | 08-2011 |
| Cilt No | 67 |
| Sayı | 8 |
| Doi Numarası | 10.1107/S1600536811029941 |
| Makale Linki | http://scripts.iucr.org/cgi-bin/paper?S1600536811029941 |
| Atıf Sayıları | |
| WoS | 1 |
| SCOPUS | 1 |
| Google Scholar | 7 |
