Diaquabis N N diethylnicotinamide KN 1 bis 4 fluorobenzoato KO copper II
Yazarlar (5)
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
Doç. Dr. Füreya Elif ÖZTÜRKKAN Kafkas Üniversitesi, Türkiye
Vijdan Ozturk
Kafkas Üniversitesi, Türkiye
Doç. Dr. Vedat ADIGÜZEL Kafkas Üniversitesi, Türkiye
Tuncer Hokelek
Hacettepe Üniversitesi, Türkiye
Makale Türü Açık Erişim Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Acta Crystallographica Section E Structure Reports Online (Q4)
Dergi ISSN 1600-5368
Dergi Tarandığı Indeksler SCI
Makale Dili İngilizce Basım Tarihi 08-2011
Kabul Tarihi 25-07-2011 Yayınlanma Tarihi 30-07-2011
Cilt / Sayı / Sayfa 67 / 8 / – DOI 10.1107/S1600536811029941
Makale Linki http://scripts.iucr.org/cgi-bin/paper?S1600536811029941
UAK Araştırma Alanları
Anorganik Kimya
Özet
The asymmetric unit of the title mononuclear CuII complex, [Cu(C7H4FO2)2(C10H14N2O)2(H2O)2], contains one-half of the molecule. The CuII ion is located on an inversion centre, and is coordinated by two N atoms from two diethylnicotinamide ligands, two O atoms from two 4-fluorobenzoate (PFB) ligands and two water molecules in a distorted octahedral geometry. In the PFB ligand, the carboxylate group is twisted at an angle of 2.10 (14)° from the attached benzene ring. In the crystal structure, intermolecular O—H⋯O hydrogen bonds link molecules related by translation along the a axis into chains. Weak intermolecular C—H⋯O hydrogen bonds and π–π interactions between the pyridine rings of neighbouring molecules [centroid-to-centroid distance = 3.571 (2) Å] further consolidate the crystal packing.
Anahtar Kelimeler
data-to-parameter ratio = 17.6 | mean σ(CC) = 0.002 Å | R factor = 0.033 | single-crystal X-ray study | T = 100 K | wR factor = 0.099
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Diaquabis N N diethylnicotinamide KN 1 bis 4 fluorobenzoato KO copper II

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