Bis 4 fluoro benzoato 2 O O O 4 fluoro benzoic acid O bis nico tinamide N 1 copper II
Yazarlar (5)
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
Doç. Dr. Füreya Elif ÖZTÜRKKAN Kafkas Üniversitesi, Türkiye
Vijdan Ztürk
Kafkas Üniversitesi, Türkiye
Kafkas Üniversitesi, Türkiye
Bar Tercan
Karabük Üniversitesi, Türkiye
Karabük Üniversitesi, Türkiye
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
Hacettepe Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
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| Dergi Adı | Acta Crystallographica Section E Structure Reports Online (Q4) | ||
| Dergi ISSN | 1600-5368 | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 07-2011 |
| Kabul Tarihi | 31-05-2011 | Yayınlanma Tarihi | 11-06-2011 |
| Cilt / Sayı / Sayfa | 67 / 7 / – | DOI | 10.1107/S1600536811020897 |
| Makale Linki | http://scripts.iucr.org/cgi-bin/paper?S1600536811020897 | ||
| UAK Araştırma Alanları |
Anorganik Kimya
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| Özet |
| In the title CuII complex, [Cu(C7H4FO2)2(C7H5FO2)(C6H6N2O)2], the CuII cation is coordinated by two N atoms of two nicotinamide (NA) ligands, and by four O atoms from two 4-fluorobenzoate (PFB) anions and one 4-fluorobenzoic acid (PFBA) molecule, in a distorted octahedral geometry. In the molecule, two Cu—O bond lengths are significantly longer than the other two. The dihedral angles between the carboxylate groups and the adjacent benzene rings are 11.08 (14), 7.62 (13) and 5.73 (11)°, while the benzene rings are oriented at dihedral angles of 15.62 (6), 33.71 (8) and 26.60 (8)°. In the crystal structure, extensive N—H⋯O, C—H⋯F and C—H⋯O hydrogen bonds link the molecules into a three-dimensional network. π–π contacts between the benzene rings [centroid-to-centroid distances = 3.5517 (15), 3.8456 (14) and 3.9265 (13) Å] further stabilize the crystal structure. |
| Anahtar Kelimeler |
Science Direct
Bis 4 fluoro benzoato 2 O O O 4 fluoro benzoic acid O bis nico tinamide N 1 copper II
| Atıf Sayıları | |
| Web of Science | 7 |
| Scopus | 8 |
| Google Scholar | 13 |