| Yazarlar |
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye |
Doç. Dr. Füreya Elif ÖZTÜRKKAN
Kafkas Üniversitesi, Türkiye |
Vijdan Öztürk
Türkiye |
Doç. Dr. Vedat ADIGÜZEL
Kafkas Üniversitesi, Türkiye |
|
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye |
| Özet |
| In the crystal structure of the title Mn II complex, [Mn(C 7H 4BrO2) 2(C 10H 14N 2O) 2(H 2O) 2], the Mn II cation is located on an inversion center and coordinated by two diethylnicotinamide (DENA) ligands, two 4-bromobenzoate (PBB) anions and two water molecules in a distorted octahedral geometry. The dihedral angle between the carboxylate group and the adjacent benzene ring is 3.25 (14)°. In the molecule, the pyridine ring and the benzene ring are oriented at a dihedral angle of 77.24 (5)°. In the crystal, intermolecular C - H⋯O hydrogen bonds link the molecules into a twodimensional network. Weak intermolecular C - H⋯O hydrogen bonds and π-π interactions between the pyridine rings of neighbouring molecules [centroidcentroid distance = 3.537 (1) Å] further consolidate the crystal packing. |
| Anahtar Kelimeler |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale |
| Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS |
| Dergi ISSN | 2056-9890 |
| Dergi Tarandığı Indeksler | SCI |
| Makale Dili | İngilizce |
| Basım Tarihi | 09-2011 |
| Cilt No | 67 |
| Sayı | 9 |
| Doi Numarası | 10.1107/S1600536811031412 |
| Makale Linki | http://scripts.iucr.org/cgi-bin/paper?S1600536811031412 |
| Atıf Sayıları |
