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| Dergi Adı | Acta Crystallographica Section E Structure Reports Online | ||
| Dergi ISSN | 1600-5368 | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 05-2009 |
| Kabul Tarihi | 13-04-2009 | Yayınlanma Tarihi | 18-04-2009 |
| Cilt / Sayı / Sayfa | 65 / 5 / – | DOI | 10.1107/S160053680901383X |
| Makale Linki | http://scripts.iucr.org/cgi-bin/paper?S160053680901383X | ||
| UAK Araştırma Alanları |
Anorganik Kimya
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| Özet |
| The title MnII complex, [Mn(C7H4BrO2)2(C10H14N2O)2(H2O)2], is centrosymmetric. The molecule contains two 2-bromobenzoate (BB) and two diethylnicotinamide (DENA) ligands and two water molecules, all ligands being monodentate. The four O atoms in the equatorial plane around the Mn atom form a slightly distorted square-planar arrangement, while the distorted octahedral coordination is completed by the two N atoms of the DENA ligands in the axial positions. The dihedral angle between the carboxyl group and the adjacent benzene ring is 79.95 (11)°, while the pyridine and benzene rings are oriented at a dihedral angle of 45.66 (6)°. In the crystal structure, intermolecular O—H⋯O hydrogen bonds link the molecules into infinite chains. |
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