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| Dergi Adı | Acta Crystallographica Section E Structure Reports Online (Q4) | ||
| Dergi ISSN | 1600-5368 | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 11-2009 |
| Kabul Tarihi | 04-10-2009 | Yayınlanma Tarihi | 10-10-2009 |
| Cilt / Sayı / Sayfa | 65 / 11 / – | DOI | 10.1107/S1600536809040392 |
| Makale Linki | http://scripts.iucr.org/cgi-bin/paper?S1600536809040392 | ||
| UAK Araştırma Alanları |
Anorganik Kimya
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| Özet |
| The asymmetric unit of the title complex, [Ni(C6H6N2O)2(H2O)4](C7H4FO2)2, contains one-half of the complex cation with the NiII atom located on an inversion center, and a 2-fluorobenzoate (FB) counter-anion. The four O atoms in the equatorial plane around the Ni atom form a slightly distorted square-planar arrangement with an average Ni—O bond length of 2.079 Å, and the slightly distorted octahedral coordination is completed by the two N atoms of the nicotinamide (NA) ligands in the axial positions. The dihedral angle between the carboxyl group and the attached benzene ring is 28.28 (11)°, while the pyridine and benzene rings are oriented at a dihedral angle of 8.31 (4)°. In the crystal structure, O—H⋯O, N—H⋯O, C—H⋯O, and C—H⋯F hydrogen bonds link the molecules into a three-dimensional network. π–π Contacts between the pyridine and benzene rings [centroid–centroid distance = 3.626 (1) Å … |
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| Atıf Sayıları | |
| Web of Science | 4 |
| Web of Science | 8 |
| Scopus | 7 |
| Scopus | 10 |
| Google Scholar | 8 |
| Google Scholar | 11 |