Diaqua bis 2 chloro benzoato O bis N N diethyl nicotinamide N 1 nickel II
   
Yazarlar (5)
Tuncer Hökelek Hacettepe Üniversitesi, Türkiye
Hakan Dal Anadolu Üniversitesi, Türkiye
Bariş Tercan
Karabük Üniversitesi, Türkiye
Doç. Dr. Füreya Elif ÖZTÜRKKAN Kafkas Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
Makale Türü Açık Erişim Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Acta Crystallographica Section E Structure Reports Online
Dergi ISSN 1600-5368
Dergi Tarandığı Indeksler SCI
Makale Dili İngilizce Basım Tarihi 05-2009
Cilt / Sayı / Sayfa 65 / 5 / – DOI 10.1107/S1600536809014226
Makale Linki https://journals.iucr.org/e/issues/2009/05/00/ci2776/ci2776.pdf
Özet
In the monomeric and centrosymmetric title NiII complex, [Ni(C7H4ClO2)2(C10H14N2O)2(H2O)2], the NiII ion is located on an inversion center. The asymmetric unit contains one 2-chlorobenzoate ligand, one diethylnicotinamide (DENA) ligand and one coordinating water molecule, the ligands being monodentate. The four O atoms in the equatorial plane around the NiII ion form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by two N atoms of the DENA ligands in axial positions. The dihedral angle between the benzene ring and the attached carboxylate group is 87.36 (10)°, while the pyridine and benzene rings are oriented at an angle of 41.90 (5)°. In the crystal structure, intermolecular O—H⋯O hydrogen bonds link the molecules into a two-dimensional network parallel to (10\overline{1}).
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