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| Dergi Adı | Acta Crystallographica Section E Structure Reports Online | ||
| Dergi ISSN | 1600-5368 | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 05-2009 |
| Kabul Tarihi | 16-04-2009 | Yayınlanma Tarihi | 22-04-2009 |
| Cilt / Sayı / Sayfa | 65 / 5 / – | DOI | 10.1107/S1600536809014226 |
| Makale Linki | http://scripts.iucr.org/cgi-bin/paper?S1600536809014226 | ||
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Anorganik Kimya
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| Özet |
| In the monomeric and centrosymmetric title NiII complex, [Ni(C7H4ClO2)2(C10H14N2O)2(H2O)2], the NiII ion is located on an inversion center. The asymmetric unit contains one 2-chlorobenzoate ligand, one diethylnicotinamide (DENA) ligand and one coordinating water molecule, the ligands being monodentate. The four O atoms in the equatorial plane around the NiII ion form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by two N atoms of the DENA ligands in axial positions. The dihedral angle between the benzene ring and the attached carboxylate group is 87.36 (10)°, while the pyridine and benzene rings are oriented at an angle of 41.90 (5)°. In the crystal structure, intermolecular O—H⋯O hydrogen bonds link the molecules into a two-dimensional network parallel to (10\overline{1}). |
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