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Diaquabis 2 bromobenzoato O bis N N diethylnicotinamide N 1 nickel II      
Yazarlar
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
Filiz Yılmaz
Eskişehir Teknik Üniversitesi, Türkiye
Mustafa Barış Tercan
Karabük Üniversitesi, Türkiye
 Füreya Elif ÖZTÜRKKAN Füreya Elif ÖZTÜRKKAN
Kafkas Üniversitesi, Türkiye
 Hacali NECEFOĞLU Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye
Özet
In the monomeric centrosymmetric title NiII complex, [Ni(C 7H4BrO2)2(C10H 14N2O)2(H2O)2], the NiII ion is located on an inversion center. The asymmetric unit contains one 2-bromo-benzoate ligand, one diethyl-nicotinamide (DENA) ligand and one coordinated water mol-ecule. The four O atoms in the equatorial plane around the NiII ion form a slightly distorted square-planar arrangement, while the slightly distorted octa-hedral coordination is completed by two N atoms of two DENA ligands in the axial positions. The dihedral angle between the benzene ring and the attached carboxyl-ate group is 87.73 (15)°, while the pyridine and benzene rings are oriented at a dihedral angle of 42.48 (7)°. In the crystal structure, O - H⋯O hydrogen bonds link the mol-ecules into a two-dimensional network parallel to (10 ). In addition, C - H⋯O hydrogen bonds are observed.
Anahtar Kelimeler
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale
Dergi Adı ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
Dergi ISSN 2056-9890
Dergi Tarandığı Indeksler SCI
Makale Dili İngilizce
Basım Tarihi 07-2009
Cilt No 65
Sayı 7
Doi Numarası 10.1107/S1600536809021795
Makale Linki http://scripts.iucr.org/cgi-bin/paper?S1600536809021795