Diaquabis 2 bromobenzoato O bis N N diethylnicotinamide N 1 nickel II
     
Yazarlar (5)
Tuncer Hökelek Hacettepe Üniversitesi, Türkiye
Filiz Ylmaz Anadolu Üniversitesi, Türkiye
Bar Tercan Karabük Üniversitesi, Türkiye
Doç. Dr. Füreya Elif ÖZTÜRKKAN Kafkas Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
Makale Türü Açık Erişim Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Acta Crystallographica Section E Structure Reports Online (Q4)
Dergi ISSN 1600-5368
Dergi Tarandığı Indeksler SCI
Makale Dili İngilizce Basım Tarihi 07-2009
Cilt / Sayı / Sayfa 65 / 7 / – DOI 10.1107/S1600536809021795
Makale Linki https://doi.org/10.1107/s1600536809021795
Özet
In the monomeric centrosymmetric title NiII complex, [Ni(C 7H4BrO2)2(C10H 14N2O)2(H2O)2], the NiII ion is located on an inversion center. The asymmetric unit contains one 2-bromo-benzoate ligand, one diethyl-nicotinamide (DENA) ligand and one coordinated water mol-ecule. The four O atoms in the equatorial plane around the NiII ion form a slightly distorted square-planar arrangement, while the slightly distorted octa-hedral coordination is completed by two N atoms of two DENA ligands in the axial positions. The dihedral angle between the benzene ring and the attached carboxyl-ate group is 87.73 (15)°, while the pyridine and benzene rings are oriented at a dihedral angle of 42.48 (7)°. In the crystal structure, O - H⋯O hydrogen bonds link the mol-ecules into a two-dimensional network parallel to (10 ). In addition, C - H⋯O hydrogen bonds are observed.
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