Diaquabis 2 bromobenzoato O bis N N diethylnicotinamide N 1 nickel II
Yazarlar (5)
Tuncer Hökelek Hacettepe Üniversitesi, Türkiye
Filiz Ylmaz Anadolu Üniversitesi, Türkiye
Bar Tercan Karabük Üniversitesi, Türkiye
Doç. Dr. Füreya Elif ÖZTÜRKKAN Kafkas Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
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| Dergi Adı | Acta Crystallographica Section E Structure Reports Online (Q4) | ||
| Dergi ISSN | 1600-5368 | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 07-2009 |
| Cilt / Sayı / Sayfa | 65 / 7 / – | DOI | 10.1107/S1600536809021795 |
| Makale Linki | https://doi.org/10.1107/s1600536809021795 | ||
| Özet |
| In the monomeric centrosymmetric title NiII complex, [Ni(C7H4BrO2)2(C10H14N2O)2(H2O)2], the NiII ion is located on an inversion center. The asymmetric unit contains one 2-bromobenzoate ligand, one diethylnicotinamide (DENA) ligand and one coordinated water molecule. The four O atoms in the equatorial plane around the NiII ion form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by two N atoms of two DENA ligands in the axial positions. The dihedral angle between the benzene ring and the attached carboxylate group is 87.73 (15)°, while the pyridine and benzene rings are oriented at a dihedral angle of 42.48 (7)°. In the crystal structure, O—H⋯O hydrogen bonds link the molecules into a two-dimensional network parallel to (10\overline{1}). In addition, C—H⋯O hydrogen bonds are observed. |
| Anahtar Kelimeler |
Science Direct
Diaquabis 2 bromobenzoato O bis N N diethylnicotinamide N 1 nickel II
| Atıf Sayıları | |
| Google Scholar | 16 |
| Web of Science | 4 |