Diaqua bis 2 chloro benzoato kO bis nicotinamide kN1 nickel II
Yazarlar (5)
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
Hakan Dal
Anadolu Üniversitesi, Türkiye
Bar Tercan
Karabük Üniversitesi, Türkiye
Doç. Dr. Füreya Elif ÖZTÜRKKAN
Kafkas Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
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| Dergi Adı | Acta Crystallographica Section E Structure Reports Online (Q4) | ||
| Dergi ISSN | 1600-5368 | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 04-2009 |
| Cilt / Sayı / Sayfa | 65 / 4 / – | DOI | 10.1107/S1600536809011209 |
| Makale Linki | https://journals.iucr.org/e/issues/2009/04/00/xu2501/xu2501.pdf | ||
| Özet |
| The title NiII complex, [Ni(C7H4ClO 2)2(C6H6N2O) 2(H2O)2], is centrosymmetric with the Ni atom located on an inversion centre. The mol-ecule contains two 2-chloro-benzoate (CB) and two nicotinamide (NA) ligands and two water mol-ecules, all ligands being monodentate. The four O atoms in the equatorial plane around the Ni atom form a slightly distorted square-planar arrangement, while the slightly distorted octa-hedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxyl group and the adjacent benzene ring is 29.48 (16)°, while the pyridine and benzene rings are oriented at a dihedral angle of 83.16 (5)°. In the crystal structure, O - H⋯O and N - H⋯O hydrogen bonds link the mol-ecules into infinite chains. π-π Contacts between the benzene and pyridine rings [centroid-centroid distance = 3.952 (1) Å] may further stabilize the crystal structure. There is also a C - H⋯π inter-action. © 2009. |
| Anahtar Kelimeler |
Science Direct
Diaqua bis 2 chloro benzoato kO bis nicotinamide kN1 nickel II
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| WoS | 40 |
| SCOPUS | 39 |
| Google Scholar | 48 |