Tetra aqua bis nicotinamide N 1 cobalt II bis 2 fluoro benzoate
Yazarlar (5)
Doç. Dr. Füreya Elif ÖZTÜRKKAN Kafkas Üniversitesi, Türkiye
Bar Tercan
Karabük Üniversitesi, Türkiye
Ertan Ahin
Atatürk Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
Makale Türü Açık Erişim Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Acta Crystallographica Section E Structure Reports Online (Q4)
Dergi ISSN 1600-5368
Dergi Tarandığı Indeksler SCI
Makale Dili İngilizce Basım Tarihi 03-2009
Kabul Tarihi 24-02-2009 Yayınlanma Tarihi 28-02-2009
Cilt / Sayı / Sayfa 65 / 3 / – DOI 10.1107/S1600536809006771
Makale Linki http://scripts.iucr.org/cgi-bin/paper?S1600536809006771
UAK Araştırma Alanları
Anorganik Kimya
Özet
The title complex, [Co(C6H6N2O)2(H2O)4](C7H4FO2)2, contains one Co(II) atom (site symmetry \overline1), two monodentate nicotinamide (NA) ligands, four coordinated water molecules and two 2-fluorobenzoate (FB) anions. The four O atoms in the equatorial plane around the Co atom form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxyl group and the adjacent benzene ring is 29.8 (3)°, while the pyridine and benzene rings are oriented at a dihedral angle of 7.97 (12)°. In the crystal structure, molecules are linked by O—H⋯O, N—H⋯O and N—H⋯F hydrogen bonds, forming an infinite three-dimensional network. π–π Contacts between the pyridine and benzene rings [centroid–centroid distance = 3.673 (3) Å] may further stabilize the crystal …
Anahtar Kelimeler
Science Direct
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
Tetra aqua bis nicotinamide N 1 cobalt II bis 2 fluoro benzoate

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