Yazarlar |
Onur Şahin
Sinop Üniversitesi, Türkiye |
Orhan Büyükgüngör
Ondokuz Mayıs Üniversitesi, Türkiye |
Dursun Ali Köse
Hitit Üniversitesi, Türkiye |
Doç. Dr. Füreya Elif ÖZTÜRKKAN
Kafkas Üniversitesi, Türkiye |
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye |
Özet |
The title compound [Co(C7H4O2I)2(C10H14N2O)2(H2O)2] is a two-dimensional hydrogen-bonded supramolecular complex. The complex crystallizes in the triclinic space group P1 with unit-cell parameters a = 7.2964(13), b = 8.6047(17), c = 16.745(3)Å, α= 93.034(15), β = 101.574(15), γ = 111.975(14)° and Z = 1. The Co(II) ion resides on a centre of symmetry, and is in an octahedral coordination environment comprising two pyridyl N atoms, two carboxylate O atoms and two O atoms from water molecules. Intermolecular C-H·O and O-H···O hydrogen bonds produce R22(16), R22(18) and R22(20) rings, which lead to one-dimensional polymeric chains. An extensive two-dimensional network of C-H···O and O-H···O hydrogen bonds, p-p and C-H···π interactions are responsible for crystal stabilization. 2008 © The Japan Society for Analytical Chemistry. |
Anahtar Kelimeler |
Makale Türü | Özgün Makale |
Makale Alt Türü | Diğer hakemli uluslarası dergilerde yayımlanan tam makale |
Dergi Adı | Analytical Sciences: X-ray Structure Analysis Online |
Dergi ISSN | 1348-2238 |
Dergi Tarandığı Indeksler | CAS database |
Makale Dili | İngilizce |
Basım Tarihi | 10-2008 |
Cilt No | 24 |
Sayı | 10 |
Sayfalar | 253 / 254 |
Doi Numarası | 2056-9890 |
Makale Linki | https://www.jstage.jst.go.jp/article/analscix/24/0/24_0_x253/_pdf/-char/ja |