Synthesis and crystal structure of diaquabis 4 iodinebenzoato kO bis nicotinamide kN cobalt II
Yazarlar (5)
Ondokuz Mayis Üniversitesi, Türkiye
Ondokuz Mayis Üniversitesi, Türkiye
Hacettepe Üniversitesi, Türkiye
Doç. Dr. Füreya Elif ÖZTÜRKKAN
Kafkas Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
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| Makale Alt Türü | Diğer hakemli uluslarası dergilerde yayınlanan tam makale |
| Dergi Adı | Analytical Sciences X Ray Structure Analysis Online |
| Dergi ISSN | 1348-2238 |
| Dergi Tarandığı Indeksler | CAS database |
| Makale Dili | İngilizce |
| Basım Tarihi | 10-2008 |
| Cilt No | 24 |
| Sayı | 10 |
| DOI Numarası | 10.2116/analscix.24.x253 |
| Makale Linki | https://www.jstage.jst.go.jp/article/analscix/24/0/24_0_x253/_pdf/-char/ja |
| Özet |
| The title compound [Co(C7H4O2I)2(C10H14N2O)2(H2O)2] is a two-dimensional hydrogen-bonded supramolecular complex. The complex crystallizes in the triclinic space group P1 with unit-cell parameters a = 7.2964(13), b = 8.6047(17), c = 16.745(3)Å, α= 93.034(15), β = 101.574(15), γ = 111.975(14)° and Z = 1. The Co(II) ion resides on a centre of symmetry, and is in an octahedral coordination environment comprising two pyridyl N atoms, two carboxylate O atoms and two O atoms from water molecules. Intermolecular C-H·O and O-H···O hydrogen bonds produce R22(16), R22(18) and R22(20) rings, which lead to one-dimensional polymeric chains. An extensive two-dimensional network of C-H···O and O-H···O hydrogen bonds, p-p and C-H···π interactions are responsible for crystal stabilization. 2008 © The Japan Society for Analytical Chemistry. |
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BM Sürdürülebilir Kalkınma Amaçları
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| Google Scholar | 3 |