Diaquabis 4 bromo benzoato O bis N N diethyl nicotinamide N 1 zinc II
Yazarlar (4)
Öğr. Gör. Asli Öztürk Hacettepe Üniversitesi, Türkiye
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
Doç. Dr. Füreya Elif ÖZTÜRKKAN Kafkas Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
Makale Türü Açık Erişim Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Acta Crystallographica Section E Structure Reports Online (Q4)
Dergi ISSN 1600-5368
Dergi Tarandığı Indeksler SCI
Makale Dili İngilizce Basım Tarihi 09-2008
Kabul Tarihi 22-08-2008 Yayınlanma Tarihi 30-08-2008
Cilt / Sayı / Sayfa 64 / 9 / – DOI 10.1107/S1600536808027074
Makale Linki http://scripts.iucr.org/cgi-bin/paper?S1600536807018442
UAK Araştırma Alanları
Anorganik Kimya
Özet
The title compound, [Zn(C7H4BrO2)2(C10H14N2O)2(H2O)2], is a monomeric complex with the ZnII atom lying on an inversion center. It contains two 4-bromobenzoate, two diethylnicotinamide ligands and two water molecules, all of which are monodentate. The four O atoms in the equatorial plane around the Zn atom form a slightly distorted square-planar arrangement, while the distorted octahedral geometry is completed by two N atoms in the axial positions. The methyl group of one of the ethyl groups is disordered over two positions, with occupancies of ca 0.65 and 0.35. The two aromatic rings are oriented at an angle of 77.22 (14)°. In the crystal structure, O—H⋯O hydrogen bonds link the molecules into chains along the a axis.
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