| Yazarlar |
Öznur Dinçel
Türkiye |
|
Mustafa Barış Tercan
Karabük Üniversitesi, Türkiye |
Füreya Elif ÖZTÜRKKAN
Kafkas Üniversitesi, Türkiye |
Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye |
|
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye |
| Özet |
| In the title complex, [Co(C7H4ClO2)2(C6H6N2O)2(H2O)2], the CoII cation is located on an inversion center and is coordinated by two 2-chlorobenzoate anions, two nicotinamide (NA) ligands and two water molecules. The four O atoms in the equatorial plane around the CoII cation form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two pyridine N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxylate group and the adjacent benzene ring is 29.7 (4)°, while the pyridine and benzene rings are oriented at a dihedral angle of 83.17 (15)°. Intramolecular O - H⋯O hydrogen bonding occurs between the carboxylate group and coordinating water molecule. In the crystal, intermolecular N - H⋯O, O - H⋯O and weak C - H⋯O hydrogen bonds link the molecules into a three-dimensional network. © 2013 Dincel et al. |
| Anahtar Kelimeler |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | ESCI dergilerinde yayımlanan tam makale |
| Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE |
| Dergi ISSN | 2056-9890 |
| Dergi Tarandığı Indeksler | Ceramic Abstracts, Chemical Abstracts, Cambridge Structural Database, Emerging Sources Citation Index, Inorganic Crystal Structure Database, INSPEC, Medline, Metals Abstracts/METADEX , Scopus |
| Makale Dili | İngilizce |
| Basım Tarihi | 03-2013 |
| Cilt No | 69 |
| Sayı | 3 |
| Doi Numarası | 10.1107/S1600536813004984 |
| Makale Linki | http://scripts.iucr.org/cgi-bin/paper?S1600536813004984 |
| Atıf Sayıları | |
| Google Scholar | 14 |
