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| Dergi Adı | Acta Crystallographica Section E Structure Reports Online | ||
| Dergi ISSN | 1600-5368 | ||
| Dergi Tarandığı Indeksler | Ceramic Abstracts, Chemical Abstracts, Cambridge Structural Database, Emerging Sources Citation Index, Inorganic Crystal Structure Database, INSPEC, Medline, Metals Abstracts/METADEX , Scopus | ||
| Makale Dili | İngilizce | Basım Tarihi | 03-2013 |
| Kabul Tarihi | 20-02-2013 | Yayınlanma Tarihi | 28-02-2013 |
| Cilt / Sayı / Sayfa | 69 / 3 / – | DOI | 10.1107/S1600536813004984 |
| Makale Linki | http://scripts.iucr.org/cgi-bin/paper?S1600536813004984 | ||
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Anorganik Kimya
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| Özet |
| In the title complex, [Co(C7H4ClO2)2(C6H6N2O)2(H2O)2], the CoII cation is located on an inversion center and is coordinated by two 2-chlorobenzoate anions, two nicotinamide (NA) ligands and two water molecules. The four O atoms in the equatorial plane around the CoII cation form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two pyridine N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxylate group and the adjacent benzene ring is 29.7 (4)°, while the pyridine and benzene rings are oriented at a dihedral angle of 83.17 (15)°. Intramolecular O—H⋯O hydrogen bonding occurs between the carboxylate group and coordinating water molecule. In the crystal, intermolecular N—H⋯O, O—H⋯O and weak C—H⋯O hydrogen bonds link the molecules into a three-dimensional network. |
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| Google Scholar | 4 |