Synthesis, spectral, thermal, structural, optical characterization,and Hirshfeld surface analysis of N,N’‑diethylnicotinamide complexes of Mn(II) and Co(II) 4‑cyanobenzoates
Yazarlar (7)
Doç. Dr. Mustafa SERTÇELİK Kafkas Üniversitesi, Türkiye
Doç. Dr. Füreya Elif ÖZTÜRKKAN Kafkas Üniversitesi, Türkiye
Mustafa Yüksek Kafkas Üniversitesi, Türkiye
Ayhan Elmalı Ankara Üniversitesi, Türkiye
Dr. Öğr. Üyesi Ömer AYDOĞDU Kafkas Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
Tuncer Hökelek Hacettepe Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Chemical Papers (Q4) | ||
| Dergi ISSN | 0366-6352 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 04-2020 |
| Cilt / Sayı / Sayfa | 74 / 6 / 2021–2033 | DOI | 10.1007/s11696-019-01040-0 |
| Makale Linki | https://link.springer.com/article/10.1007/s11696-019-01040-0 | ||
| Özet |
| Two new complexes, [M(4-CNB)2(DENA)2(H2O)2] (where M: Co and Mn, 4-CNB = 4-cyanobenzoate and DENA = N,N’-diethylnicotinamide), were synthesized and characterized using different techniques (elemental analysis, FT-IR Spectroscopy, single-crystal X-ray diffraction, and TGA/DTA analysis). Looking at the crystal structure of the complexes, the metal atoms are coordinated by two nitrogen atoms from two DENA ligands, two carboxyl oxygen atoms from two 4-cyanobenzoate anions, and two oxygen atoms from two water molecules, and the complexes have distorted octahedral geometry around the metal atom center. Both complexes were crystallized with the P-1 space group in the triclinic system. The linear absorption and emission features of the complexes were recorded by UV–Vis and fluorescence spectrophotometers, respectively. Linear absorption and emission results of the complexes showed … |
| Anahtar Kelimeler |
| 4-cyanobenzoic acid | Hirshfeld surface analysis | Metal complex | N,N’-diethylnicotinamide | Optical characterization | X-ray diffraction |
| Atıf Sayıları | |
| Google Scholar | 3 |
| Web of Science | 1 |