Crystal structure and Hirshfeld surface analysis of hexakis(μ-benzoato-κ2O:O’)bis(pyridine-3-carbonitrile- κN1 )trizinc(II)
Yazarlar (5)
Tuncer Hökelek Hacettepe Üniversitesi, Türkiye
Doç. Dr. Füreya Elif ÖZTÜRKKAN Kafkas Üniversitesi, Türkiye
Doç. Dr. Mustafa SERTÇELİK Kafkas Üniversitesi, Türkiye
Çiǧdem Şahin Yenice Kafkas Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
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| Dergi Adı | Acta Crystallographica Section E Crystallographic Communications (Q4) | ||
| Dergi ISSN | 2056-9890 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 12-2017 |
| Cilt / Sayı / Sayfa | 73 / 1 / 1966–1970 | DOI | 10.1107/S2056989017016899 |
| Makale Linki | https://journals.iucr.org/e/issues/2017/12/00/nk2240/nk2240.pdf | ||
| Özet |
| The asymmetric unit of the title complex, [Zn3(C7H5O2)6(C6H4N2)2], contains one half of the complex molecule, i.e. one and a half ZnII cations, three benzoate (Bnz) and one pyridine-3-carbonitrile (Cpy) molecule; the Bnz anions act as bidentate ligands through the carboxylate O atoms, while the Cpy ligand acts as a monodentate N(pyridine)-bonding ligand. The complete centrosymmetric trinuclear complex thus comprises a linear array of three ZnII cations. The central ZnII cation shows an octahedral coordination and is bridged to each of the terminal ZnII cations by three Bnz anions. By additional coordination of the CPy ligand, the terminal ZnII cations adopt a trigonal–pyramidal coordination environment. In the crystal, the Bnz anions link to the Cpy N atoms via weak C—H⋯N hydrogen bonds, forming a two-dimensional network. C—H⋯π and π–π interactions [between the benzene and pyridine rings of adjacent … |
| Anahtar Kelimeler |
| crystal structure | transition metal complexes of benzoic acid derivatives | zinc(II) |
| Atıf Sayıları | |
| Google Scholar | 2 |
| Web of Science | 1 |
| Scopus | 1 |