Bis 2 fluorobenzoato 1 2 2 O O 2 fluorobenzoato 1 2 O O 2 fluorobenzoato 2 O dinicotinamide 1 N 1 2 N 1 dizinc II 2 fluorobenzoic acid 1 1
Yazarlar (5)
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
Hacettepe Üniversitesi, Türkiye
Filiz Ylmaz
Anadolu Üniversitesi, Türkiye
Anadolu Üniversitesi, Türkiye
Bar Tercan
Karabük Üniversitesi, Türkiye
Karabük Üniversitesi, Türkiye
Doç. Dr. Füreya Elif ÖZTÜRKKAN Kafkas Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
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| Dergi Adı | Acta Crystallographica Section E Structure Reports Online (Q4) | ||
| Dergi ISSN | 1600-5368 | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 12-2009 |
| Kabul Tarihi | 12-11-2009 | Yayınlanma Tarihi | 21-11-2009 |
| Cilt / Sayı / Sayfa | 65 / 12 / – | DOI | 10.1107/S1600536809048089 |
| Makale Linki | http://scripts.iucr.org/cgi-bin/paper?S1600536809048089 | ||
| UAK Araştırma Alanları |
Anorganik Kimya
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| Özet |
| The asymmetric unit of the title compound, [Zn2(C7H4FO2)4(C6H6N2O)2]·C7H5FO2, consists of a binuclear ZnII complex bridged by two carboxyl groups of 2-fluorobenzoate (FB) anions and a 2-fluorobenzoic acid molecule. The two bridging FB anions, one chelating FB anion and one nicotinamide (NA) ligand coordinate to one Zn cation with a distorted square-pyramidal geometry, while the two bridging FB anions, one monodentate FB anion and one NA ligand coordinate to the other Zn cation with a distorted tetrahedral geometry. Within the binuclear molecule, the pyridine rings are oriented at a dihedral angle of 19.41 (14)°. In the crystal structure, the uncoordinated 2-fluorobenzoic acid molecules are linked by O—H⋯O hydrogen bonding, forming centrosymmetric supramolecular dimers. Intermolecular N—H⋯O hydrogen bonds link the complex molecules into a three-dimensional network. The π–π contacts … |
| Anahtar Kelimeler |
Science Direct
Bis 2 fluorobenzoato 1 2 2 O O 2 fluorobenzoato 1 2 O O 2 fluorobenzoato 2 O dinicotinamide 1 N 1 2 N 1 dizinc II 2 fluorobenzoic acid 1 1
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| Web of Science | 11 |
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| Google Scholar | 10 |