| Makale Türü |
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| Dergi Adı | Acta Crystallographica Section E Structure Reports Online (Q4) | ||
| Dergi ISSN | 1600-5368 | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 09-2010 |
| Cilt / Sayı / Sayfa | 66 / 9 / – | DOI | 10.1107/S1600536810032630 |
| Makale Linki | https://journals.iucr.org/e/issues/2010/09/00/im2218/im2218.pdf | ||
| Özet |
| In the mononuclear title compound, [Co(C7H4BrO 2)2(C10H14N2O) 2(H2O)2], the CoII ion is located on a crystallographic inversion center. The asymmetric unit is completed by one 2-bromobenzoate anion, one diethylnicotinamide (DENA) ligand and one coordinated water molecule; all ligands are monodentate. The four O atoms in the equatorial plane around CoII form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two pyridine N atoms of the DENA ligands in axial positions. The dihedral angle between the carboxylate group and the attached benzene ring is 84.7 (1)°; the pyridine and benzene rings are oriented at a dihedral angle of 43.64 (6)°. In the crystal structure, intermolecular O-H⋯O and C-H⋯O hydrogen bonds link the molecules into a three-dimensional network. |
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