Yazarlar |
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye |
Güner Saka
Hitit Üniversitesi, Türkiye |
Mustafa Barış Tercan
Karabük Üniversitesi, Türkiye |
Doç. Dr. Füreya Elif ÖZTÜRKKAN
Kafkas Üniversitesi, Türkiye |
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye |
Özet |
In the mononuclear title compound, [Co(C7H4BrO 2)2(C10H14N2O) 2(H2O)2], the CoII ion is located on a crystallographic inversion center. The asymmetric unit is completed by one 2-bromobenzoate anion, one diethylnicotinamide (DENA) ligand and one coordinated water molecule; all ligands are monodentate. The four O atoms in the equatorial plane around CoII form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two pyridine N atoms of the DENA ligands in axial positions. The dihedral angle between the carboxylate group and the attached benzene ring is 84.7 (1)°; the pyridine and benzene rings are oriented at a dihedral angle of 43.64 (6)°. In the crystal structure, intermolecular O-H⋯O and C-H⋯O hydrogen bonds link the molecules into a three-dimensional network. |
Anahtar Kelimeler |
Makale Türü | Özgün Makale |
Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale |
Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS |
Dergi ISSN | 2056-9890 |
Dergi Tarandığı Indeksler | SCI |
Makale Dili | İngilizce |
Basım Tarihi | 09-2010 |
Cilt No | 66 |
Sayı | 9 |
Doi Numarası | 10.1107/S1600536810032630 |
Makale Linki | http://scripts.iucr.org/cgi-bin/paper?S1600536810032630 |
Atıf Sayıları | |
WoS | 1 |
SCOPUS | 1 |
Google Scholar | 12 |
Google Scholar | 7 |