| Makale Türü |
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| Dergi Adı | Acta Crystallographica Section E Structure Reports Online | ||
| Dergi ISSN | 1600-5368 | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 05-2009 |
| Cilt / Sayı / Sayfa | 65 / 5 / – | DOI | 10.1107/S1600536809015645 |
| Makale Linki | https://journals.iucr.org/e/issues/2009/05/00/xu2517/xu2517.pdf | ||
| Özet |
| The title ZnII complex, [Zn(C7H4BrO2)2(C6H6N2O)2(H2O)2], is centrosymmetric with the Zn atom on an inversion center. The molecule contains two 2-bromobenzoate (BB) and two nicotinamide (NA) ligands and two coordinated water molecules, all ligands being monodentate. The four O atoms in the equatorial plane around the Zn atom form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxyl group and the adjacent benzene ring is 31.14 (12)°, while the pyridine and benzene rings are oriented at a dihedral angle of 83.54 (5)°. In the crystal structure, O—H⋯O and N—H⋯O hydrogen bonds link the molecules into infinite chains. A weak C—H⋯π interaction is also present. |
| Anahtar Kelimeler |
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| Google Scholar | 57 |
| Web of Science | 37 |
| Scopus | 5 |