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Diaqua bis 2 chloro benzoato O bis N N diethyl nicotinamide N 1 manganese II     
Yazarlar
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
Hakan Dal
Anadolu Üniversitesi, Türkiye
Mustafa Barış Tercan
Karabük Üniversitesi, Türkiye
Doç. Dr. Füreya Elif ÖZTÜRKKAN Doç. Dr. Füreya Elif ÖZTÜRKKAN
Kafkas Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye
Özet
In the monomeric title complex, [Mn(C7H4ClO2)2(C10H14N2O)2(H2O)2], the MnII atom is located on a crystallographic centre of inversion. The asymmetric unit contains one 2-chloro-benzoate (CB) ligand, one diethyl-nicotinamide (DENA) ligand and one coordinated water mol-ecule, all ligands being monodentate. The four O atoms in the equatorial plane around the Mn atom form a slightly distorted square-planar arrangement, while the slightly distorted octa-hedral coordination is completed by the two pyridine N atoms of the DENA ligands in the axial positions. The dihedral angle between the carboxyl group and the adjacent benzene ring is 77.9 (11)°, while the pyridine and benzene rings are oriented at a dihedral angle of 45.94 (5)°. In the crystal structure, inter-molecular O - H⋯O hydrogen bonds link the mol-ecules into infinite chains.
Anahtar Kelimeler
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale
Dergi Adı ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
Dergi ISSN 2056-9890
Dergi Tarandığı Indeksler SCI
Makale Dili İngilizce
Basım Tarihi 05-2009
Cilt No 65
Sayı 5
Doi Numarası 10.1107/S160053680901318X
Makale Linki http://scripts.iucr.org/cgi-bin/paper?S160053680901318X
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
WoS 10
SCOPUS 11
Diaqua bis 2 chloro benzoato O bis N N diethyl nicotinamide N 1 manganese II

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