Diaqua bis 2 chloro benzoato O bis N N diethyl nicotinamide N 1 manganese II
    
Yazarlar (5)
T. Hökelek Hacettepe Üniversitesi, Türkiye
H. Dal Anadolu Üniversitesi, Türkiye
B. Tercan Karabük Üniversitesi, Türkiye
Doç. Dr. Füreya Elif ÖZTÜRKKAN Kafkas Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
Makale Türü Açık Erişim Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Acta Crystallographica Section E Structure Reports Online
Dergi ISSN 1600-5368
Dergi Tarandığı Indeksler SCI
Makale Dili İngilizce Basım Tarihi 05-2009
Cilt / Sayı / Sayfa 65 / 5 / – DOI 10.1107/S160053680901318X
Makale Linki https://journals.iucr.org/e/issues/2009/05/00/im2110/im2110.pdf
Özet
In the monomeric title complex, [Mn(C7H4ClO2)2(C10H14N2O)2(H2O)2], the MnII atom is located on a crystallographic centre of inversion. The asymmetric unit contains one 2-chloro-benzoate (CB) ligand, one diethyl-nicotinamide (DENA) ligand and one coordinated water mol-ecule, all ligands being monodentate. The four O atoms in the equatorial plane around the Mn atom form a slightly distorted square-planar arrangement, while the slightly distorted octa-hedral coordination is completed by the two pyridine N atoms of the DENA ligands in the axial positions. The dihedral angle between the carboxyl group and the adjacent benzene ring is 77.9 (11)°, while the pyridine and benzene rings are oriented at a dihedral angle of 45.94 (5)°. In the crystal structure, inter-molecular O - H⋯O hydrogen bonds link the mol-ecules into infinite chains.
Anahtar Kelimeler