Yazarlar |
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye |
Hakan Dal
Anadolu Üniversitesi, Türkiye |
Mustafa Barış Tercan
Karabük Üniversitesi, Türkiye |
Doç. Dr. Füreya Elif ÖZTÜRKKAN
Kafkas Üniversitesi, Türkiye |
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye |
Özet |
In the monomeric title complex, [Mn(C7H4ClO2)2(C10H14N2O)2(H2O)2], the MnII atom is located on a crystallographic centre of inversion. The asymmetric unit contains one 2-chloro-benzoate (CB) ligand, one diethyl-nicotinamide (DENA) ligand and one coordinated water mol-ecule, all ligands being monodentate. The four O atoms in the equatorial plane around the Mn atom form a slightly distorted square-planar arrangement, while the slightly distorted octa-hedral coordination is completed by the two pyridine N atoms of the DENA ligands in the axial positions. The dihedral angle between the carboxyl group and the adjacent benzene ring is 77.9 (11)°, while the pyridine and benzene rings are oriented at a dihedral angle of 45.94 (5)°. In the crystal structure, inter-molecular O - H⋯O hydrogen bonds link the mol-ecules into infinite chains. |
Anahtar Kelimeler |
Makale Türü | Özgün Makale |
Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale |
Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS |
Dergi ISSN | 2056-9890 |
Dergi Tarandığı Indeksler | SCI |
Makale Dili | İngilizce |
Basım Tarihi | 05-2009 |
Cilt No | 65 |
Sayı | 5 |
Doi Numarası | 10.1107/S160053680901318X |
Makale Linki | http://scripts.iucr.org/cgi-bin/paper?S160053680901318X |
Atıf Sayıları | |
WoS | 10 |
SCOPUS | 11 |